| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Koper, Mtm Marc
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2022Electrochemical CO2 Reduction on Gas Diffusion Electrodescitations
- 2020CO2electroreduction on bimetallic Pd-In nanoparticlescitations
- 2020Cathodic Disintegration as an Easily Scalable Method for the Production of Sn-and Pb-Based Catalysts for CO2Reductioncitations
- 2019Structural principles to steer the selectivity of the electrocatalytic reduction of aliphatic ketones on platinumcitations
- 2019Mechanistic study of the electrosynthesis of propylene carbonate from propylene oxide and CO2 on copper electrodescitations
- 2018Spectroscopic investigation of the electrosynthesis of diphenyl carbonate from CO and phenol on gold electrodescitations
- 2017Spectroscopic observation of a hydrogenated CO dimer intermediate during CO reduction on Cu(100) electrodescitations
- 2017Structure- and potential-dependent cation effects on CO reduction at copper single-crystal electrodescitations
- 2016In situ spectroscopic study of CO2 electroreduction at copper electrodes in acetonitrilecitations
- 2008Cubic MgH2 stabilized by alloying with transition metals : a density functional theory studycitations
- 2005CO oxidation on stepped Rh[n(111)x(111)] single crystal electrodes: Anion effects on CO surface mobilitycitations
- 2003Stripping voltammetry and chronoamperometry of an adsorbed species with repulsive lateral interactionscitations
- 2002Dynamics of CO at the solid/liquid interface studied by modeling and simulation of CO electro-oxidation on Pt and PtRu electrodescitations
Places of action
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article
Mechanistic study of the electrosynthesis of propylene carbonate from propylene oxide and CO2 on copper electrodes
Abstract
<p>Efficient and selective electrosynthesis of propylene carbonate can be performed by the reaction of carbon dioxide with propylene oxide at copper electrodes. In this paper, we investigate this electrochemical reaction by using cyclic voltammetry, Fourier transform infrared spectroscopy and high-performance liquid chromatography in order to unravel details of the catalytic mechanism of the reaction. The combination of the results obtained by these different techniques allows the exclusion of different reduced forms of CO<sub>2</sub>, such as CO and (bi)carbonates, as possible carboxylation agents. Moreover, the results also indicate that electrochemical activation of the propylene oxide by ring opening is not the initial step for this reaction, as no product was detected when a current was not applied in presence of “activated propylene oxide” and CO<sub>2</sub>. Our results show that the reaction is initiated by the activation of CO<sub>2</sub> to CO<sub>2</sub><sup>.−</sup>, which then attacks the epoxide to form the cyclic carbonate. This work also gives evidence for the non-catalytic nature of the synthesis of the cyclic carbonate because its formation also occurs on other metals such as gold and platinum in the same range of applied currents. This result clearly indicates the potential of in situ electrochemical techniques in the mechanistic investigation of electrosynthesis reactions.</p>