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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Napporn, Teko
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023A Route to Complex Materials Consisting of Multiple Crystalline Phases Ir‐Ru‐Ir x Ru 1‐x O 2 as Multifunctional Electrocatalystscitations
- 2023Replacing oxygen evolution reaction by glycerol electrooxidation on Rh modified Ni(OH)2/C for energy-efficient hydrogen productioncitations
- 2023A Route to Complex Materials Consisting of Multiple Crystalline Phases Ir‐Ru‐Ir$_x$Ru$_{1‐x}$O$_2$ as Multifunctional Electrocatalystscitations
- 2022An FTIR study of the electrooxidation of C2 and C3 alcohols on carbon-supported PdxRhy in alkaline mediumcitations
- 2022Tuning the Tin Oxide-Carbon Composite Support to Deposit Rh Nanoparticles for Glycerol-to-Carbonate Electro-Conversioncitations
- 2022A step forward: hydrogen production on cobalt molybdenum sulfide electrocatalyst in anion exchange membrane water electrolyzercitations
- 2021Cost-effective functionalization of Vulcan XC-72 by using the intermittent microwave heating process as nanocatalyst support for ethanol electrooxidation in acid mediacitations
- 2021Bridging the two ends: Designing materials to bridge electronic conductivity and catalytic activity in an electrochemical energy converter
- 2020Insight into the Electrooxidation Mechanism of Ethylene Glycol on Palladium‐Based Nanocatalysts: In Situ FTIRS and LC‐MS Analysiscitations
- 2018Performance and In-Situ FTIR Evaluation of Pt−Sn/C Electrocatalysts with Several Pt : Sn Atomic Ratios for the Ethanol Oxidation Reaction in Acidic Mediacitations
- 2018Metal Loading Effect on the Activity of Co 3 O 4 /N-Doped Reduced Graphene Oxide Nanocomposites as Bifunctional Oxygen Reduction/Evolution Catalystscitations
Places of action
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article
Metal Loading Effect on the Activity of Co 3 O 4 /N-Doped Reduced Graphene Oxide Nanocomposites as Bifunctional Oxygen Reduction/Evolution Catalysts
Abstract
The development of effective and stable reversible oxygen electrodes is of upmost importance for bringing regenerative energy storage and conversion systems to a commercial reality. However, realization of such electrodes is motivated by low activity and instability of the current electrocatalysts working for both water splitting and oxygen reduction. Herein, we report a series of Co3O4/graphene-based catalysts with different Co mass loadings prepared by using a facile one-step hydrothermal route. N-doped reduced graphene oxide (NRGO) was utilized as a substrate for the deposition of oxide particles. The structural properties and surface composition of the different materials were investigated by powder X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy measurements. The effect of Co mass loading on the morphostructural properties of oxide nanoparticles and also on their electroactivity towards the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) was addressed. This study revealed the optimum range for metal loading on the graphene substrate. Co3O4/NRGO with a Co mass loading of 30 wt.% exhibits the highest activity towards ORR and OER, with a reversibility criterion of 763 mV. This work is very helpful for the electrocatalysis community, and will allow effective catalysts to be developed for high-power metal/air battery or regenerative fuel cell systems, based on earth-abundant and scalable electro-catalysts.