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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Blanchard, Philippe
French National Centre for Scientific Research
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023A new G-quadruplex-specific photosensitizer inducing genome instability in cancer cells by triggering oxidative DNA damage and impeding replication fork progressioncitations
- 2021Anisotropic confinement of chromophores induces second-order nonlinear optics in a nanoporous photonic metamaterialcitations
- 2020Synthesis, characterization and use of benzothioxanthene imide based dimerscitations
- 2020Synthesis, characterization and use of benzothioxanthene imide based dimerscitations
- 2019Physical mechanisms involved in the formation and operation of memory devices based on a monolayer of gold nanoparticles-polythiophene hybrid materialscitations
- 2019Triphenylamine and some of its derivatives as versatile building blocks for organic electronic applicationscitations
- 2018Triphenylamine-Based Push–Pull σ–C$_{60}$ Dyad As Photoactive Molecular Material for Single-Component Organic Solar Cells: Synthesis, Characterizations, and Photophysical Propertiescitations
- 2017Simply Complex: The Efficient Synthesis of an Intricate Molecular Acceptor for High-Performance Air-Processed and Air-Tested Fullerene-Free Organic Solar Cellscitations
- 2015Engineered Electronic Contacts for Composite Electrodes in Li Batteries Using Thiophene-based Molecular Junctionscitations
- 2014Synthesis of Hybrid Electroactive Materials by Low-Potential Electropolymerization of Gold Nanoparticles Capped with Tailored EDOT-Thiophene Precursor Unitscitations
- 2012In situ redox functionalization of composite electrodes for high power-high energy electrochemical storage systems via a non-covalent approachcitations
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article
Synthesis of Hybrid Electroactive Materials by Low-Potential Electropolymerization of Gold Nanoparticles Capped with Tailored EDOT-Thiophene Precursor Units
Abstract
The synthesis of gold nanoparticles (GNPs) capped with alkanethiols with terminal bithiophenic polymerizable groups, consisting of 3,4-ethylenedioxythiophene (EDOT) and 3-alkylsulfanylthiophene, is described. Transmission electron microscopy (TEM) and light diffusion show that these stabilized GNPs have an average size of 2–3 nm with low polydispersity. The electrochemical behavior of C10S-Au is investigated in dichloromethane in the presence of Bu4NPF6. The results show that these capped GNPs undergo straightforward and efficient electropolymerization under potentiodynamic or potentiostatic conditions. TEM images show that the electrodeposited films of the composite material present a very homogeneous structure, in which the size of the GNPs incorporated into the polythiophene matrix is unchanged. Results of cyclic voltammetry and spectroelectrochemistry obtained on polymer films deposited on platinum electrodes and transparent indium tin oxide electrodes, respectively, show that the reversible charging–discharging process and electrochromic behavior typical of poly(thiophenes) are preserved in the hybrid electroactive material.