| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Saha, Rajat
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Multifunctional Interpenetrated 3D Supramolecular Structure Based on 1D Coordination Polymers: Selective Adsorption, Magnetism, Optical Property, Theoretical Analysis, and Electrical Conductivitycitations
- 2024A 3D Coordination Polymer Based on Syn-Anti Bridged [Mn(RCOO)2]n Chains Showing Spin-Canting with High Coercivity and an Ordering Temperature of 14 Kcitations
- 2024Simultaneous hydroxido-, nitrato-, and phenoxido-bridged binuclear copper Schiff base complex for green catalytic click chemistry: Synthesis, structure, Hirshfeld surface analysis, theoretical study and photoluminescence spectracitations
- 2024Carbazole diester strapped calix[4]pyrrole: Synthesis, anion binding and self-assembly based on ion pair recognitioncitations
- 2024Rhodamine hydrazide-linked naphthalimide derivative: Selective naked eye detection of Cu2+, S2− and understanding the therapeutic potential of the copper complex as an anti-cervical cancer agentcitations
- 2023Electrocatalytic Water Oxidation by Hydrolytically Stable Metal‐Organic Frameworks at Both Neutral and Alkaline Medium: Inverse Relation of Dimensionality with Catalytic Activitycitations
- 2023Multifunctional Interpenetrated 3D Supramolecular Structure Based on 1D Coordination Polymers: Selective Adsorption, Magnetism, Optical Property, Theoretical Analysis, and Electrical Conductivitycitations
- 2023A 3D Coordination Polymer Based on Syn-Anti Bridged [Mn(RCOO)2]n Chains Showing Spin-Canting with High Coercivity and an Ordering Temperature of 14 Kcitations
- 2022Simultaneous presence of mono- and bi-cationic bipyridyls within a metal-organic supramolecular host: crystal structure, spectral and Hirshfeld surface analysiscitations
- 2022Solvent‐ and Substrate‐Induced Chiroptical Inversion in Amphiphilic, Biocompatible Glycoconjugate Supramolecules: Shape‐Persistent Gelation, Self‐Healing, and Antibacterial Activitycitations
- 2021Photo-responsive Schottky Diode Behavior of a Donor-Acceptor Co-crystal with Violet Blue Light Emissioncitations
- 2014Synthesis, characterization, X-ray crystallography and antimicrobial activities of new Co(III) and Cu(II) complexes with a pyrazole based Schiff base ligandcitations
Places of action
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article
Electrocatalytic Water Oxidation by Hydrolytically Stable Metal‐Organic Frameworks at Both Neutral and Alkaline Medium: Inverse Relation of Dimensionality with Catalytic Activity
Abstract
<jats:title>Abstract</jats:title><jats:p>Catalyst development for water splitting to afford hydrogen as a green source of energy is one of the major areas of research in the pursuit of sustainable energy technology solution. Herein, the electrocatalytic water oxidation behaviour of two different Co‐pdc (H<jats:sub>2</jats:sub>pdc=pyridine‐2,5‐dicarboxylic acid) based metal‐organic frameworks (MOFs) of different dimensionalities (2D and 1D) is reported. 2D‐MOF {[Co(pdc)(H<jats:sub>2</jats:sub>O)<jats:sub>2</jats:sub>] ⋅ H<jats:sub>2</jats:sub>O}n acts as the mother which transforms into daughter 1D‐MOF {[Co(pdc)(H<jats:sub>2</jats:sub>O)<jats:sub>2</jats:sub>] ⋅ 7H<jats:sub>2</jats:sub>O}n via consecutive dehydration and rehydration. Within 2D‐MOF, the Co<jats:sup>2+</jats:sup> shows six coordinated octahedral geometry with two coordinated water molecules and for the 1D‐MOF, Co<jats:sup>2+</jats:sup> shows five coordinated square pyramidal geometry having two coordinated water molecules and one open metal site. Both the MOFs show excellent stability over a pH range of 3 to 11 even after 24 hours and show OER activity from neutral to alkaline medium. The MOFs retain their crystalline structure even after OER at neutral pH but eventually gets decomposed; but they are converted into their (oxy)hydroxides at pH 14. Interestingly, 1D MOF shows superior activity in both neutral and alkaline medium over the 2D framework for OER due to presence of open metal sites, better electrical conductivity and larger electrochemically active surface area.</jats:p>