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| Azevedo, Nuno Monteiro |
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Jain, Suman L.
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article
Photochemical Oxidative Coupling of 2‐Naphthols using a Hybrid Reduced Graphene Oxide/Manganese Dioxide Nanocomposite under Visible‐Light Irradiation
Abstract
<jats:title>Abstract</jats:title><jats:p>We describe a simple, cost‐effective, efficient, and high‐yielding photocatalytic approach for the oxidative self‐dimerization of 2‐naphthols using a semiconductor–metal hybrid that consists of intercalated manganese dioxide nanoparticles in reduced graphene oxide (rGO/MnO<jats:sub>2</jats:sub>) under visible‐light irradiation. The desired photocatalyst was synthesized in a single step by mixing MnO<jats:sub>2</jats:sub> nanoparticles with rGO ultrasonically. The hybrid photocatalyst exhibited a significantly higher activity than neat MnO<jats:sub>2</jats:sub> nanoparticles and rGO, which is believed to be because of the synergistic effect of its components. To our knowledge, this hybrid rGO/MnO<jats:sub>2</jats:sub> nanocomposite is the first heterogeneous, green photocatalyst for the oxidative coupling of 2‐naphthols under mild conditions.</jats:p>