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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Garcia-Araez, Nuria
University of Southampton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023Combined electrochemical, XPS, and STXM study of lithium nitride as a protective coating for lithium metal and lithium–sulfur batteriescitations
- 2023A polyacrylonitrile shutdown film for prevention of thermal runaway in lithium-ion cells
- 2022Impact of Compression on the Electrochemical Performance of the Sulfur/Carbon Composite Electrode in Lithium-Sulfur Batteriescitations
- 2022Operando characterization of active surface area and passivation effects on sulfur-carbon composites for lithium-sulfur batteriescitations
- 2022Operando characterization of active surface area and passivation effects on sulfur-carbon composites for lithium-sulfur batteriescitations
- 2022Impact of compression on the electrochemical performance of the sulfur/carbon composite electrode in lithium–sulfur batteriescitations
- 2022Impact of compression on the electrochemical performance of the sulfur/carbon composite electrode in lithium–sulfur batteriescitations
- 2021Negating the interfacial resistance between solid and liquid electrolytes for next-generation lithium batteriescitations
- 2021Cell design for the electrodeposition of polyacrylonitrile onto graphite composite electrodes for use in lithium-ion cellscitations
- 2021Cell design for the electrodeposition of polyacrylonitrile onto graphite composite electrodes for use in lithium-ion cellscitations
- 2018Understanding and development of olivine LiCoPO4 cathode materials for lithium-ion batteriescitations
Places of action
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article
Impact of compression on the electrochemical performance of the sulfur/carbon composite electrode in lithium–sulfur batteries
Abstract
<p>While lithium-sulfur batteries theoretically have both high gravimetric specific energy and volumetric energy density, only its specific energy has been experimentally demonstrated to surpass that of the state-of-the-art lithium-ion systems at cell level. One major reason for the unrealized energy density is the low capacity density of the highly porous sulfur/carbon composite as the positive electrode. In this work, mechanical compression at elevated temperature is demonstrated to be an effective method to increase the capacity density of the electrode by at least 90 % and moreover extends its cycle life. Distinct impacts of compression on the resistance profiles of electrodes with different thickness are investigated by tortuosity factors derived from both electrochemical impedance spectroscopy, X-ray computed tomography and kinetic analysis based on operando X-ray diffraction. The results highlights the importance of a homogeneous electrode structure highlight lithium-sulfur system.</p>