| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Janek, Jürgen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (54/54 displayed)
- 2024SEI growth on Lithium metal anodes in solid-state batteries quantified with coulometric titration time analysis
- 2024Effect of salt selection and molar ratio in molten salt synthesis of single-crystalline LiNiO₂
- 2024The Impact of Microstructure on Filament Growth at the Sodium Metal Anode in All‐Solid‐State Sodium Batteries
- 2024Dualism of Remarkable Magnesium Ion Conduction with Low Activation Energy over a Wide Temperature Range versus Limited Stability of the Hybrid Composite Electrolyte Mg‐MOF‐74/Mg<i>X</i><sub>2</sub>/Propylene Carbonate
- 2023Non‐Linear Kinetics of The Lithium Metal Anode on Li6PS5Cl at High Current Density: Dendrite Growth and the Role of Lithium Microstructure on Creepcitations
- 2023Overcoming Anode Instability in Solid‐State Batteries through Control of the Lithium Metal Microstructurecitations
- 2023Atomic Layer Deposition Derived Zirconia Coatings on Ni‐Rich Cathodes in Solid‐State Batteries: Correlation Between Surface Constitution and Cycling Performance
- 2023Current‐Dependent Lithium Metal Growth Modes in “Anode‐Free” Solid‐State Batteries at the Cu|LLZO Interfacecitations
- 2023SEI growth on Lithium metal anodes in solid-state batteries quantified with coulometric titration time analysiscitations
- 2023In situ study of electrochemical activation and surface segregation of the SOFC electrode material La0.75Sr0.25r0.5 Mn0.5O3±delta
- 2023Simple cathode design for Li-S batteries : cell performance and mechanistic insights by in operando X-ray diffraction
- 2023Kinetics and Pore Formation of the Sodium Metal Anode on NASICON‐Type Na$_{3.4}$ Zr$_2$Si$_{2.4}$P$_{0.6}$O$_{12}$ for Sodium Solid‐State Batteries
- 2023Investigation of the Stability of the Poly(ethylene oxide) | LiNi$_{1‐x‐y}$Co$_x$Mn$_y$O$_2$ Interface in Solid‐State Batteries
- 2023Interface Design Enabling Stable Polymer/Thiophosphate Electrolyte Separators for Dendrite-Free Lithium Metal Batteries
- 2023In Situ Observation of Room‐Temperature Magnesium Metal Deposition on a NASICON/IL Hybrid Solid Electrolytecitations
- 2023The effect of configurational entropy on acoustic emission of P2-type layered oxide cathodes for sodium-ion batteriescitations
- 2023Evaluation and Improvement of the Stability of Poly(ethylene oxide)-based Solid-state Batteries with High-Voltage Cathodes
- 2023Amorphous and highly nonstoichiometric titania (TiOx) thin films close to metal-like conductivity
- 2023Nonisothermal transport properties of alpha-Ag2 + deltaS : Partial thermopowers of electrons and ions, the soret effect and heats of transport
- 2023The Impact of Microstructure on Filament Growth at the Sodium Metal Anode in All‐Solid‐State Sodium Batteriescitations
- 2023Deposition of Sodium Metal at the Copper‐NaSICON Interface for Reservoir‐Free Solid‐State Sodium Batteriescitations
- 2023Evaluating the Use of Critical Current Density Tests of Symmetric Lithium Transference Cells with Solid Electrolytescitations
- 2023Electrochemically induced oxygen spillover and diffusion on Pt(111): PEEM imaging and kinetic modelling
- 2023Identification of Lithium Compounds on Surfaces of Lithium Metal Anode with Machine-Learning-Assisted Analysis of ToF-SIMS Spectracitations
- 2023Structure, site symmetry and spin-orbit coupled magnetism of a Ca12Al14O33 mayenite single crystal substituted with 0.26 at.% Ni
- 2023Electrocatalysis on Pt/YSZ electrodes
- 2023Electrochemical activation of molecular nitrogen at the Ir/YSZ interface
- 2023Impact of the Chlorination of Lithium Argyrodites on the Electrolyte/Cathode Interface in Solid-State Batteries
- 2022Atomic Layer Deposition Derived Zirconia Coatings on Ni‐Rich Cathodes in Solid‐State Batteries: Correlation Between Surface Constitution and Cycling Performancecitations
- 2022In Situ Investigation of Lithium Metal–Solid Electrolyte Anode Interfaces with ToF‐SIMScitations
- 2022Influence of the Polymer Structure and its Crystallization on the Interface Resistance in Polymer-LATP and Polymer-LLZO Hybrid Electrolytes
- 2022Increasing the Pressure‐Free Stripping Capacity of the Lithium Metal Anode in Solid‐State‐Batteries by Carbon Nanotubescitations
- 2022Understanding the formation of antiphase boundaries in layered oxide cathode materials and their evolution upon electrochemical cycling
- 2022Kinetics and Pore Formation of the Sodium Metal Anode on NASICON‐Type Na$_{3.4}$ Zr$_2$Si$_{2.4}$P$_{0.6}$O$_{12}$ for Sodium Solid‐State Batteriescitations
- 2022Advanced Analytical Characterization of Interface Degradation in Ni-Rich NCM Cathode Co-Sintered with LATP Solid Electrolytecitations
- 2022Functionalization of Ti-40Nb implant material with strontium by reactive sputtering
- 2021Understanding the formation of antiphase boundaries in layered oxide cathode materials and their evolution upon electrochemical cyclingcitations
- 2021Working principle of an ionic liquid interlayer during pressureless lithium stripping on Li6.25Al0.25La3Zr2O12 (LLZO) garnet‐type solid electrolytecitations
- 2021Reaction of Li1.3Al0.3Ti1.7(PO4)3 and LiNi0.6Co0.2Mn0.2O2 in co-sintered composite cathodes for solid-state batteriescitations
- 2021Increased performance improvement of lithium-ion batteries by dry powder coating of high-nickel NMC with nanostructured fumed ternary lithium metal oxidescitations
- 2020From LiNiO₂ to Li₂NiO₃ : Synthesis, Structures and Electrochemical Mechanisms in Li-Rich Nickel Oxidescitations
- 2019Amorphous versus Crystalline $Li_3PS_{4}$: Local Structural Changes during Synthesis and Li Ion Mobilitycitations
- 2018High electrical conductivity and high porosity in a Guest@MOF material : Evidence of TCNQ ordering within Cu3BTC2 microporescitations
- 2017Embroidered Copper Microwire Current Collector for Improved Cycling Performance of Silicon Anodes in Lithium-Ion Batteriescitations
- 2017Functionalization of Ti-40Nb implant material with strontium by reactive sputteringcitations
- 2016An EMF cell with a nitrogen solid electrolyte-on the transference of nitrogen ions in yttria-stabilized zirconia
- 2015An approach for transparent and electrically conducting coatings ; a transparent plastic varnish with nanoparticulate magnetic additives
- 2015Ionic Conductivity of Mesostructured Yttria-Stabilized Zirconia Thin Films with Cubic Pore Symmetry — On the Influence of Water on the Surface Oxygen Ion Transportcitations
- 2014Amorphous and highly nonstoichiometric titania (TiOx) thin films close to metal-like conductivitycitations
- 2014A metallic room-temperature oxide ion conductorcitations
- 2013Quantification of calcium content in bone by using ToF-SIMS–a first approach
- 2011Mesoporous tin-doped indium oxide thin films: Effect of mesostructure on electrical conductivity
- 2011Electrochemical activation of molecular nitrogen at the Ir/YSZ interface.citations
- 2011Structure and dynamics of the fast lithium ion conductor "li 7La3Zr2O12"
Places of action
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article
Working principle of an ionic liquid interlayer during pressureless lithium stripping on Li6.25Al0.25La3Zr2O12 (LLZO) garnet‐type solid electrolyte
Abstract
No pressure: This work demonstrates the working principle of an ionic liquid interlayer to enhance the stripping performance of lithium metal in contact with a garnet solid electrolyte. Detailed analysis, including galvanostatic electrochemical impedance spectroscopy and cryogenic FIB-SEM, shows that pores forming in lithium metal during stripping are compensated to a great extent, which improves the stripping performance up to over 15 mAh cm−2. Solid-state-batteries employing lithium metal anodes promise high theoretical energy and power densities. However, morphological instability occurring at the lithium/solid–electrolyte interface when stripping and plating lithium during cell cycling needs to be mitigated. Vacancy diffusion in lithium metal is not sufficiently fast to prevent pore formation at the interface above a certain current density during stripping. Applied pressure of several MPa can prevent pore formation, but this is not conducive to practical application. This work investigates the concept of ionic liquids as “self-adjusting” interlayers to compensate morphological changes of the lithium anode while avoiding the use of external pressure. A clear improvement of the lithium dissolution process is observed as it is possible to continuously strip more than 70 μm lithium (i. e., 15 mAh cm−2 charge) without the need for external pressure during assembly and electrochemical testing of the system. The impedance of the investigated electrodes is analyzed in detail, and contributions of the different interfaces are evaluated. The conclusions are corroborated with morphology studies using cryo-FIB-SEM and chemical analysis using XPS. This improves the understanding of the impedance response and lithium stripping in electrodes employing liquid interlayers, acting as a stepping-stone for future optimization.