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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Mcinnes, Eric J. L.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Metal-carbon bonding in early lanthanide substituted cyclopentadienyl complexes probed by pulsed EPR spectroscopycitations
- 2024Two‐ and Three‐Spin Hybrid Inorganic‐Organic [2]Rotaxanes Containing Metallated Salen Groups
- 2021High Ammonia Adsorption in MFM-300 Materials:Dynamics and Charge Transfer in Host–Guest Bindingcitations
- 2021Catalytic decomposition of NO 2 over a copper-decorated metal–organic framework by non-thermal plasmacitations
- 2021High Ammonia Adsorption in MFM-300 Materialscitations
- 2021Catalytic decomposition of NO2 over a copper-decorated metal–organic framework by non-thermal plasmacitations
- 2021Catalytic decomposition of NO2 over a copper-decorated metal–organic framework by non-thermal plasmacitations
- 2020Quantitative Electro-Reduction of CO2 to Liquid Fuel over Electro-Synthesized Metal-Organic Frameworkscitations
- 2020Quantitative Electro-Reduction of CO2 to Liquid Fuel over Electro-Synthesized Metal-Organic Frameworkscitations
- 2019Iodine adsorption in a redox-active metal-organic frameworkcitations
- 2016Emergence of comparable covalency in isostructural cerium(IV)- and uranium(IV)-carbon multiple bondscitations
- 2015Copper Lanthanide Phosphonate Cages: Highly Symmetric {Cu(3)Ln(9)P(6)} and {Cu(6)Ln(6)P(6)} Clusters with C-3v and D-3h Symmetrycitations
- 2007Tuning intermolecular magnetic exchange interactions in the solids C xF2x(CNSSS)2(AsF6)2: Structural, EPR, and magnetic characterization of dimeric (x = 2, 4) diradicalscitations
- 2006Incorporation of fused tetrathiafulvalenes (TTFs) into polythiophene architectures: Varying the electroactive dominance of the TTF species in hybrid systemscitations
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article
Two‐ and Three‐Spin Hybrid Inorganic‐Organic [2]Rotaxanes Containing Metallated Salen Groups
Abstract
Mono- and bis-salen functionalised [2]rotaxanes have been synthesised from the esterification of [2]rotaxanes containing phenol-terminated threads (salen = N,N′-bis(salicylidene)ethylenediamine). The [2]rotaxanes have general formula [RH][Cr<sub>7</sub>NiF<sub>8</sub>(O<sub>2</sub>C<sup><i>t</i></sup>Bu)<sub>16</sub>], where [RH]<sup>+</sup> is a thread with a central secondary ammonium site that templates a [Cr<sub>7</sub>NiF<sub>8</sub>(O<sub>2</sub>C<sup><i>t</i></sup>Bu)<sub>16</sub>]<sup>− </sup>ring. The threads are terminated at one or both ends by carboxylic acid functionalised salen groups. The {M(salen)} groups can be free-base [M = (H+)2] or metallated [M = Cu<sup>2</sup>+, Ni<sup>2+</sup>, (VO)<sup>2+</sup>]. The [2]rotaxanes have been characterised by single crystal XRD and solid- and solution-state EPR spectroscopy. Where two paramagnetic M ions are involved [M = Cu<sup>2+</sup> and/or (VO)<sup>2+</sup>] the [2]rotaxanes contain three electron spin S = ½ centres, since the {Cr<sub>7</sub>Ni} ring has an S = ½ ground state which is well isolated at low temperatures. These three-spin [2]rotaxanes have been characterised in solution by pulsed dipolar EPR spectroscopies (DEER, also known as PELDOR, and RIDME). The M···M and M···{Cr<sub>7</sub>Ni} interactions measured are consistent with dipolar interactions and also with the distances from single crystal XRD.<br/><br/>