| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Sobolev, Alexandre
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023Structure of Bis(Lidocaine) Tetrachloridoferrate(III) Chloride
- 2023Inert Transition Metal Ion Complexes in Organic Synthesiscitations
- 2021Uranyl complexes of p-t-butylcalix[8]arene as H-bond acceptors—subtle effects of the donorscitations
- 2021Crystal structure of hexakis(N, N-dimethylformamide-κ O)iron(III) μ-chlorido-bis(trichloridocadmium)citations
- 2020Structure Reassignment of Echinosulfone A and the Echinosulfonic Acids A-D Supported by Single-Crystal X-ray Diffraction and Density Functional Theory Analysiscitations
- 2020Structural Systematics of Lanthanide(iii) Picrate Solvatescitations
- 2020Synthesis and Structures of Bis- A nd Tris-(triphenylarsine)gold(i) Iodides
- 2019Crystal structures of an imidazo[1,5-a]pyridinium-based ligand and its (C13H12N3)(2)[CdI4] hybrid saltcitations
- 2008Nanoporous materials based on heteroleptic bilayers built up from bisphosphonium, p-sulfonatocalix[4]arene ionscitations
- 2007Variable temperature Hirshfeld surface analysis of interdigitated calix[6]arene bearing O-alkyl C18 linear chainscitations
- 2003Cation movement and phase transitions in KTP isostructures; X-ray study of sodium-doped KTP at 10.5 Kcitations
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article
Inert Transition Metal Ion Complexes in Organic Synthesis
Abstract
<p>Single-crystal X-ray diffraction studies for a variety of metal ion complexes of functionalised sarcophagines (sarcophagine=sar=3,6,10,13,16,19-hexa-azabicyclo[6.6.6]icosane) have further confirmed not only that the form of the metal ion/sar unit is unique for each metal, albeit with a sensitivity of the conformation to the associated counter anions, but also that for any given metal and ligand substituent, the dimensions (bond lengths and angles) of the complex and the substituent at the secondary nitrogen centres do not differ significantly from those of the isolated components. Despite this, where the substituent contains reactive sites, the reactivity differs markedly from that of their form in an uncoordinated substrate. Rationalisations are offered for these differences, in part through the use of Hirshfeld surface analysis of the intermolecular interactions. The kinetic inertness of the complexes means that the metal ions can be considered to act as regioselective protecting groups.</p>