| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Widmer, Roland
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Asymmetric molecular adsorption and regioselective bond cleavage on chiral PdGa crystalscitations
- 2024Asymmetric Molecular Adsorption and Regioselective Bond Cleavage on Chiral PdGa Crystalscitations
- 2023Electronic Decoupling and Single‐Molecule Charging of C<sub>60</sub> on h‐BN/Rh(111)citations
- 2023Electronic decoupling and single‐molecule charging of C 60 on h‐BN/Rh(111)citations
- 2022Asymmetric elimination reaction on chiral metal surfacescitations
- 2021Asymmetric azide-alkyne Huisgen cycloaddition on chiral metal surfacescitations
- 2020Near‐enantiopure trimerization of 9‐Ethynylphenanthrene on a chiralmetal surfacecitations
- 2018Oxidized Co–Sn nanoparticles as long-lasting anode materials for lithium-ion batteriescitations
- 2015Highly enantioselective adsorption of small prochiral molecules on a chiral intermetallic compoundcitations
- 2015Monodisperse SnSb nanocrystals for Li-ion and Na-ion battery anodes: synergy and dissonance between Sn and Sbcitations
- 2014Adsorption of small hydrocarbons on the three-fold PdGa surfaces: the road to selective hydrogenationcitations
- 2014Ensemble effect evidenced by CO adsorption on the 3-fold PdGa surfacescitations
- 2012Surface investigation of intermetallic PdGa(1̅ 1̅ 1̅)citations
- 2012How to control the selectivity of palladium-based catalysts in hydrogenation reactions: the role of subsurface chemistrycitations
- 2009Structure investigation of the (100) surface of the orthorhombic Al13Co4 crystalcitations
- 2009Growth of crystalline TiO 2 by plasma enhanced chemical vapor depositioncitations
- 2007Electrolytic in situ STM investigation of h-BN-nanomeshcitations
Places of action
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article
Electronic Decoupling and Single‐Molecule Charging of C<sub>60</sub> on h‐BN/Rh(111)
Abstract
<jats:title>Abstract</jats:title><jats:p>A detailed understanding of the interaction between molecules and 2D materials is crucial to implement molecular films into next‐generation 2D material‐organic hybrid devices effectively. In this regard, energy level alignment and charge transfer processes are particularly relevant. This work investigates the interplay between a hexagonal boron nitride (h‐BN) monolayer on an Rh(111) single crystal and self‐assembled C<jats:sub>60</jats:sub> thin films. The influence of the corrugated topography and electrostatic surface potential originating from the h‐BN/Rh(111) Moiré superstructure on the electronic level alignment and charging characteristics of C<jats:sub>60</jats:sub> is being studied. A combination of scanning tunneling microscopy/spectroscopy (STM/STS) and a theoretical tight‐binding approach is used to gain insight into the C<jats:sub>60</jats:sub> bandstructure formation and electronic decoupling of specific C<jats:sub>60</jats:sub>. This decoupling results from adsorption site‐dependent variations of the molecular energy level alignment, which controls the strength of intermolecular hybridization. The decoupling of specific C<jats:sub>60</jats:sub> enables the direct observation of single‐electron charging processes via STS and Kelvin probe force microscopy. The charging of the C<jats:sub>60</jats:sub> is enabled by combining two gating mechanisms: the electrostatic surface potential of the monolayer h‐BN/Rh(111) Moiré and the electric field of the STM tip.</jats:p>