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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hassine, Tarek
Processes and Engineering in Mechanics and Materials
in Cooperation with on an Cooperation-Score of 37%
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Publications (4/4 displayed)
- 2024Effect of processing conditions on morphology and mechanical damage in glass‐reinforced polypropylene compositecitations
- 2022Modeling of viscoelastic behavior of a shape memory polymer blendcitations
- 2021Modeling of viscoelastic behavior of a shape memory polymer blendcitations
- 2018Finite element analysis of hydrogen effects on superelastic NiTi shape memory alloys: Orthodontic applicationcitations
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article
Modeling of viscoelastic behavior of a shape memory polymer blend
Abstract
<jats:title>Abstract</jats:title><jats:p>Shape memory effect (SME) of polymers is a property that concerns both, macroscopic and microscopic changes. The variation of internal polymer properties such, as molecular weight (<jats:italic>M</jats:italic><jats:sub>w</jats:sub>), rigidity, and viscoelasticity could alter its SME. In this study, a bi‐parabolic model with six parameters is used to describe the viscoelastic behavior of a shape memory polymer (SMP) blend (40% poly(caprolactone), PCL/60% Styrene–Butadiene–Styrene) with different PCL <jats:italic>M</jats:italic><jats:sub>w</jats:sub>. These parameters are determined using the Cole–Cole method. Modeling curves (<jats:italic>E</jats:italic>″ = <jats:italic>f</jats:italic> (<jats:italic>E</jats:italic>′)) will be then compared to experimental data from dynamical mechanical analysis (DMA) tests. It is shown that the bi‐parabolic model predicts well the behavior of the SMP mixture for different <jats:italic>M</jats:italic><jats:sub>w</jats:sub> of PCL. Afterwards, the evolution of the model parameters with the <jats:italic>M</jats:italic><jats:sub>w</jats:sub> of PCL is investigated. It is revealed that, when <jats:italic>M</jats:italic><jats:sub>w</jats:sub> of PCL drops, the relaxation modulus <jats:italic>E</jats:italic><jats:sub>0</jats:sub> increases. This result proves that the rigidity of the SMP blend rises with <jats:italic>M</jats:italic><jats:sub>w</jats:sub> declines.</jats:p>