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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Olmos, Dania
Universidad Carlos III de Madrid
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2022Airbrushed Polysulfone (PSF)/Hydroxyapatite (HA) Nanocomposites: Effect of the Presence of Nanoparticles on Mechanical Behaviorcitations
- 2020Consolidation of Fir Wood by Poly(vinyl butyral-co-vinyl alcohol-co-vinyl acetate) Treatment: Study of Surface and Mechanical Characteristicscitations
- 2019PVDF/BaTiO<sub>3</sub>/carbon nanotubes ternary nanocomposites prepared by ball milling: Piezo and dielectric responsescitations
- 2018Cyclodextrin-Grafted TiO2 Nanoparticles: Synthesis, Complexation Capacity, and Dispersion in Polymeric Matricescitations
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article
PVDF/BaTiO<sub>3</sub>/carbon nanotubes ternary nanocomposites prepared by ball milling: Piezo and dielectric responses
Abstract
<jats:title>ABSTRACT</jats:title><jats:p>Nanocomposites based on poly(vinylidene fluoride) (PVDF) filled with barium titanate, BaTiO<jats:sub>3</jats:sub>, (BT) particles, and multiwalled carbon nanotubes (MWCNTs) were prepared by high‐energy ball milling (HEBM) and subsequent hot pressing. This method of materials preparation allowed obtaining uniform dispersions of the nanofillers. The influence of the particles on the polymer structure and morphology was studied. To understand the origin of changes in the PVDF properties, thermal and electrical behaviors of the PVDF/BT/MWCNT nanocomposites were studied as a function of composition. The addition of BT, MWCNT, or its mixture had not any influence on the PVDF polymorphism. However, calorimetric results pointed out that the presence of the nanofillers exerted nucleation mainly ascribed to the surface to volume ratio of the nanoparticles. The capacitance of the composites increased as the nanofiller content increased, being the effect mainly dependent on the surface to volume ratio of the nanoparticles. The dielectric behavior of the materials as a function of frequency was modeled by a Debye equivalent circuit only below the percolation threshold respect to the amount of MWCNT. The piezoelectric behavior of the ternary nanocomposites was highly affected by the incorporation of the nanofillers only when high dielectric losses occurred above the percolation threshold. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. <jats:bold>2019</jats:bold>, <jats:italic>136</jats:italic>, 47788.</jats:p>