| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Catel, Yohann
Ivoclar Vivadent (Liechtenstein)
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Evaluation of novel urethane dimethacrylates as crosslinkers for the development of fracture tough dental materials containing a poly(ε‐caprolactone)‐polydimethylsiloxane‐poly(ε‐caprolactone) triblock copolymercitations
- 2024Color-Stable Formulations for 3D-Photoprintable Dental Materialscitations
- 2023Synthesis of original polymeric hydroperoxides as innovative oxidizing agents for self-cure dental materials
- 2023Group transfer polymerization in bulk methacrylatescitations
- 2022Influence of Block Copolymer Concentration and Resin Crosslink Density on the Properties of UV‐Curable Methacrylate Resin Systemscitations
- 2017Synthesis of acidic vinylcyclopropanes for dental applicationscitations
- 2017Development of low‐shrinkage composites based on novel crosslinking vinylcyclopropanescitations
- 2017Evaluation of Difunctional Vinylcyclopropanes as Reactive Diluents for the Development of Low‐Shrinkage Compositescitations
- 2016Bis(4‐methoxybenzoyl)diethylgermane: A Highly Efficient Photoinitiator for the Polymerization of Vinylcyclopropanescitations
- 2009Synthesis, photopolymerization, and adhesive properties of new bisphosphonic acid monomers for dental applicationcitations
- 2008Synthesis, photopolymerization and adhesive properties of new hydrolytically stable phosphonic acids for dental applicationscitations
- 2008Synthesis, photopolymerization and adhesive properties of new hydrolytically stable phosphonic acids for dental applicationscitations
Places of action
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article
Development of low‐shrinkage composites based on novel crosslinking vinylcyclopropanes
Abstract
<jats:title>ABSTRACT</jats:title><jats:p>Polymerization shrinkage of methacrylate‐based dental composites remains a major concern in restorative dentistry. Cyclic monomers that undergo ring‐opening polymerization are known to exhibit reduced polymerization shrinkage compared to methacrylates. In this article, the synthesis of four crosslinking 1,1‐disubstituted 2‐vinylcyclopropanes bearing rigid spacers is described. These monomers were synthesized by esterification of 1‐ethoxycarbonyl‐2‐vinylcyclopropane‐1‐carboxylic acid with the corresponding diols. The photopolymerization kinetics of these monomers was investigated by photo‐differential scanning calorimeter using bis(4‐methoxybenzoyl)diethylgermane as the photoinitiator. The synthesized vinylcyclopropanes (VCPs) were shown to be more reactive than the frequently used reactive diluent triethylene glycol dimethacrylate. Composites based on these VCPs showed good mechanical properties and exhibited a significantly reduced volumetric shrinkage and shrinkage stress compared to a corresponding dimethacrylate‐based restorative material. This work highlights the excellent potential of VCPs as alternatives to methacrylates in the development of low‐shrinkage dental composites. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. <jats:bold>2017</jats:bold>, <jats:italic>134</jats:italic>, 45577.</jats:p>