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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Schawe, Jürgen E. K.
ETH Zurich
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024The glass transition temperature of anhydrous amorphous calcium carbonate
- 2024The glass transition temperature of anhydrous amorphous calcium carbonatecitations
- 2023Glass transition temperatures and crystallization kinetics of a synthetic, anhydrous, amorphous calcium-magnesium carbonatecitations
- 2023Fast differential scanning calorimetry to mimic additive manufacturing processing: specific heat capacity analysis of aluminium alloyscitations
- 2022Kinetics of the Glass Transition of Silica-Filled Styrene–Butadiene Rubber: The Effect of Resins
- 2021Kinetics of the glass transition of styrene-butadiene-rubber : Dielectric spectroscopy and fast differential scanning calorimetry
- 2020Thermodynamics of polymorphism in a bulk metallic glasscitations
- 2019Existence of multiple critical cooling rates which generate different types of monolithic metallic glasscitations
- 2017Nucleation efficiency of fillers in polymer crystallization studied by fast scanning calorimetry: Carbon nanotubes in polypropylenecitations
- 2016Solid–solid phase transitions via melting in metalscitations
- 2016Cooling rate dependence of the crystallinity at nonisothermal crystallization of polymers: A phenomenological modelcitations
- 2015Dynamic mechanical properties of very thin adhesive jointscitations
- 2015The Gibbs free energy difference between a supercooled melt and the crystalline phase of polymerscitations
- 2014Vitrification in a wide cooling rate range: The relations between cooling rate, relaxation time, transition width, and fragilitycitations
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article
Cooling rate dependence of the crystallinity at nonisothermal crystallization of polymers: A phenomenological model
Abstract
<jats:title>ABSTRACT</jats:title><jats:p>The cooling rate dependence of the crystallinity of polymers is investigated via the example of different technical polypropylenes using fast scanning calorimetry (FSC) in a cooling rate range between 1 and 5000 K s<jats:sup>−1</jats:sup>. In the slower cooling rate range (below 100 K s<jats:sup>−1</jats:sup>) the crystallinity increases slightly with decreasing cooling rate. Above cooling at 100 K s<jats:sup>−1</jats:sup> the crystallinity decreases substantially and vanishes at the critical cooling rate. We describe this behavior using a simplified model with two components: the generic crystallinity function and the retardation function. For a mathematical description, we use empirically fitted functions that describe the cooling rate dependence of the crystallinity and the critical cooling rate. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. <jats:bold>2016</jats:bold>, <jats:italic>133</jats:italic>, 42977.</jats:p>