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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Virtanen, Suvi
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2019Understanding the cross-linking reactions in highly oxidized graphene/epoxy nanocomposite systemscitations
- 2016Dielectric breakdown strength and electrical conductivity of low density polyethylene octylnanosilica composite
- 2015Large-area dielectric breakdown performance of polymer films:Part II: Interdependence of filler content, processing and breakdown performance in polypropylene-silica nanocompositescitations
- 2015Bimodal dielectric nanoparticles and nanocomposites
- 2015Balanced nanocomposite thermosetting materials for HVDC and AC applications
- 2014Structure and dielectric breakdown strength of nano calcium carbonate/polypropylene compositescitations
- 2014Improved dielectric breakdown strength using bimodal functionalized silica nanoparticles
- 2014Dielectric breakdown strength of epoxy bimodal-polymer-brush-grafted core functionalized silica nanocompositescitations
- 2014Influence of low amounts of nanostructured silica and calcium carbonate fillers on the large-area dielectric breakdown performance of bi-axially oriented polypropylenecitations
- 2013Structural studies of dielectric polymer nanocomposites
- 2011Characterization of octamethylsilsesquioxane (CH3)8Si8O12 fillers in polypropene matrix
- 2010Dielectric properties and partial discharge endurance of polypropylene-silica nanocompositecitations
Places of action
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article
Structure and dielectric breakdown strength of nano calcium carbonate/polypropylene composites
Abstract
Nanodielectrics, a 21st-century phenomena, is envisioned to be the answer for material challenges in progressive high-voltage technology. It is well known that the proper dispersion of nanoparticles plays a key role in improving the dielectric properties of a material, but to understand where changes in the properties of a material originate, it is also essential to reveal the multiscale structure of the material. In this study, the dielectric permittivity, breakdown strength, and structure of nano calcium carbonate (nano-CaCO3)/polypropylene composites with 1.8–8.1 wt % doping were characterized systematically. The combined results from transmission electron microscopy, Raman microscopy, and optical microscopy show that the quality of nanodispersion was similar in all of the filler concentrations studied. However, all of the samples also contained smoothly distributed microparticles. The density of the microparticles increased exponentially when the concentration of nano-CaCO3 was increased in the manufacturing process. The dielectric direct-current breakdown of the composites had a maximum at 1.8 wt % concentration and then decreased as the filler concentration was increased. The differences could be explained by the existence of large microparticles rather than the quality of the nanoparticle dispersion; this indicated the importance of multiscale characterization