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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mcnally, G. M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2006Structure and performance of ABS-clay nanocomposites by melt compounding
- 2006Structure-property and pigment/organoclay interaction in PP nanocomposites
- 2006Structure and performance of novel acrylonitrile-styrene-acrylate nanocomposite
- 2005Polymorphism and crystallisation in metallocene PP-copolymer nanocomposites
- 2005Optimise organoclay exfoliation in polymer nanocomposites by customising the extrusion temperature gradient
- 2004Effect of phthalocyanine blue pigment on mechanical and thermal properties of polypropylene copolymerscitations
- 2004Comparison of the effect of pigments on the mechanical and thermal properties on two different catalysed propylene-ethylene random copolymers
- 2003The mechanical properties and crystallization behaviour of pigmented propylene-ethylene random copolymer
- 2003The effect of phthalocyanine pigment on the microstructural and mechanical performance of propylene-ethylene block copolymer
- 2003The structure am performance of injection moulded, pigmented polypropylene copolymers
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article
Effect of phthalocyanine blue pigment on mechanical and thermal properties of polypropylene copolymers
Abstract
<p>Samples of two commercial polypropylene copolymers, one a random copolymer and the other a block copolymer, containing 0-8wt.% phthalocyanine blue pigment were injection moulded using mould temperatures of 40°C to 80°C. Dynamic Mechanical Thermal Analysis (DMTA) and Differential Scanning Calorimeter (DSC) analysis showed the presence of different crystalline phases in each polymer, the amount of each phase changing with increasing pigment loading. With these changes in the crystalline phases there was a progressive increase in tensile modulus, storage modulus (E′) and glass transition temperature (T<sub>g</sub>) for both copolymers. Impact performance of both pigmented copolymers decreased with an increase in pigment loading and mould temperature, with the most dramatic result shown for the random copolymer. These impact results were mirrored by the fall in loss modulii of both copolymers with increasing pigment loading.</p>