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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Pourjavadi, Ali
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2024Engineering Photo-Cross-Linkable MXene-Based Hydrogels:Durable Conductive Biomaterials for Electroactive Tissues and Interfacescitations
- 2024Engineering Photo-Cross-Linkable MXene-Based Hydrogels: Durable Conductive Biomaterials for Electroactive Tissues and Interfacescitations
- 2020Immobilization of Au nanoparticles on poly(glycidyl methacrylate)‐functionalized magnetic nanoparticles for enhanced catalytic application in the reduction of nitroarenes and Suzuki reactioncitations
- 2014Protein-directed synthesis of γ-Fe2O3 nanoparticles and their magnetic properties investigationcitations
- 2012Use of a novel initiator for synthesis of amino-end functionalized polystyrene (NH 2-PS) by atom transfer radical polymerizationcitations
Places of action
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article
Immobilization of Au nanoparticles on poly(glycidyl methacrylate)‐functionalized magnetic nanoparticles for enhanced catalytic application in the reduction of nitroarenes and Suzuki reaction
Abstract
<jats:p>We report a novel strategy for the synthesis of magnetic nanocomposite for highly efficient catalysis. Poly(glycidyl methacrylate) (PGMA) chains were grafted to the surface of magnetic nanoparticles (MNPs) through surface‐initiated reversible addition‐fragmentation chain transfer polymerization. Then, the oxirane rings in the PGMA chains were opened with 2,6‐diamino pyridine (DAP) molecules as ligands to prepare the solid support. Finally, this magnetic nanocomposite was used for the immobilization of gold nanoparticles. Fourier‐transform infrared spectroscopy, X‐ray diffraction, thermogravimetric analysis, transmission electron microscopy, scanning electron microscopy, gel permeation chromatography, vibrating sample magnetometry, and atomic absorption spectroscopy were used for characterization of the catalyst. The loading of gold nanoparticles on the solid support was 0.52 mmol/g. The catalytic activity of the prepared catalyst (MNP@PGMA@DAP@Au) was evaluated for the reduction of nitro compounds and C–C coupling reaction in water. The catalyst can be easily recovered and reused seven times without significant loss of catalytic activity.</jats:p>