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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Milman, Victor
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Topics
Publications (16/16 displayed)
- 2024Trigonal Planar [PN3]4– Anion in the Nitridophosphate Oxide Ba3[PN3]Ocitations
- 2024Synthesis and Comprehensive Studies of Be‐IV‐N2 (IV=Si, Ge): Solving the Mystery of Wurtzite‐Type Pmc21 Structurescitations
- 2024Synthesis and crystal structure of acentric anhydrous beryllium carbonate Be(CO3)citations
- 2024Trigonal Planar [PN3]4− Anion in the Nitridophosphate Oxide Ba3[PN3]Ocitations
- 2023Elasticity of Dense Metal–Organic Framework Compoundscitations
- 2022Synthesis of Ultra-Incompressible Carbon Nitrides Featuring Three-Dimensional Frameworks of CN4 Tetrahedra Recoverable at Ambient Conditions
- 2022High-pressure synthesis of seven lanthanum hydrides with a significant variability of hydrogen contentcitations
- 2021Nitrosonium nitrate (NO+NO3−) structure solution using in situ single-crystal X-ray diffraction in a diamond anvil cellcitations
- 2021Nitrosonium nitrate (NO+NO3-) structure solution using in situ single-crystal X-ray diffraction in a diamond anvil cellcitations
- 2021Nitrosonium nitrate (NO$^+$NO$_3$$^{−}$) structure solution using in situ single-crystal X-ray diffraction in a diamond anvil cellcitations
- 2021Structural, Physical, and Thermodynamic Properties of Aragonitic Ca$_x$Sr$_{1–x}$ CO$_3$ Solid Solutionscitations
- 2020Novel sulfur hydrides synthesized at extreme conditionscitations
- 2020High-Pressure Polymeric Nitrogen Allotrope with the Black Phosphorus Structurecitations
- 2020Phase stabilities of MgCO$_{3}$ and MgCO$_{3}$-II studied by Raman spectroscopy, x-ray diffraction, and density functional theory calculationscitations
- 2019A new BaCa(CO3)2 polymorphcitations
- 2014Compression Behavior of $Sm_{2}Ti_{2}O_{7}$-Pyrochlore up to 50 GPa: Single-Crystal X-ray Diffraction and Density Functional Theory Calculationscitations
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article
Trigonal Planar [PN3]4– Anion in the Nitridophosphate Oxide Ba3[PN3]O
Abstract
<jats:p>Nitridophosphates, with their primary structural motif of isolated or condensed PN4 tetrahedra, meet many requirements for high performance materials. Their properties are associated with their structural diversity, which is mainly limited by this specific building block. Herein, we present the alkaline earth metal nitridophosphate oxide Ba3[PN3]O featuring a trigonal planar [PN3]4– anion. Ba3[PN3]O was obtained using a hot isostatic press by medium‐pressure high‐temperature synthesis (MP/HT) at 200 MPa and 880 °C. The crystal structure was solved and refined from single‐crystal X‐ray diffraction data in space group R‐3c (no.167) and confirmed by SEM‐EDX, magic angle spinning (MAS) NMR, vibrational spectroscopy (Raman, IR) and low‐cost crystallographic calculations (LCC). MP/HT synthesis reveals great potential by extending the structural chemistry of P to include trigonal planar [PN3]4– motifs.</jats:p>