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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Allain, Magali
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Chiral Truxene‐Based Self‐Assembled Cages: Triple Interlocking and Supramolecular Chirogenesiscitations
- 2024Chiral Truxene‐Based Self‐Assembled Cages: Triple Interlocking and Supramolecular Chirogenesis
- 2024Perovskite versus Nonperovskite: Modulating the Nature and Optical Properties of One-Dimensional Chiral Lead–Bromide Networkscitations
- 2023Halide Containing Short Organic Monocations in n = 1–4 2D Multilayered Halide Perovskite Thin Films and Crystalscitations
- 2023A new G-quadruplex-specific photosensitizer inducing genome instability in cancer cells by triggering oxidative DNA damage and impeding replication fork progressioncitations
- 2023Azido‐Functionalized Fullerenes, Perylenediimide, Perylene, and Tetraphenylethylene as Crosslinkers for Applications in Materials Sciencecitations
- 2022Synthesis and Characterization of (FA)3(HEA)2Pb3I11: A Rare Example of <1 1 0>-Oriented Multilayered Halide Perovskitescitations
- 2022Synthesis and Characterization of (FA) 3 (HEA) 2 Pb 3 I 11 : A Rare Example of <1 1 0>-Oriented Multilayered Halide Perovskitescitations
- 2021From Zero- to One-Dimensional, Opportunities and Caveats of Hybrid Iodobismuthates for Optoelectronic Applicationscitations
- 2021Old Donors for New Molecular Conductors: Combining TMTSF and BEDT-TTF with Anionic (TaF6)1−x/(PF6)x Alloyscitations
- 2020Synthesis, characterization and use of benzothioxanthene imide based dimerscitations
- 2020Synthesis, characterization and use of benzothioxanthene imide based dimerscitations
- 2020Combining Chirality and Hydrogen Bonding in Methylated Ethylenedithio-Tetrathiafulvalene Primary Diamide Precursors and Radical Cation Saltscitations
- 2020Conservation of structural arrangements and 3 : 1 stoichiometry in a series of crystalline conductors of TMTTF, TMTSF, BEDT-TTF, and chiral DM-EDT-TTF with the oxo-bis[pentafluorotantalate( v )] dianioncitations
- 2020Conservation of structural arrangements and 3 : 1 stoichiometry in a series of crystalline conductors of TMTTF, TMTSF, BEDT-TTF, and chiral DM-EDTTTF with the oxo-bis[pentafluorotantalate(V)] dianion
- 2015A Mechanofluorochromic Push-Pull Small Molecule with Aggregation-Controlled Linear and Nonlinear Optical Propertiescitations
- 2012Cyanomethylene-bis(phosphonate) as ditopical ligand: stepwise formation of a 2-D heterometallic Fe(III)-Ag(I) coordination networkcitations
- 2009Spectrometric Analyses, Structure and Voltammetric Study of Nickel(II) with N[(1E) Phenylmethylene N2[2(2Hydroxyphenylmethylene]Amino ethyl) Imidazolidin-1-yl Ethylaminecitations
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article
Chiral Truxene‐Based Self‐Assembled Cages: Triple Interlocking and Supramolecular Chirogenesis
Abstract
<jats:title>Abstract</jats:title><jats:p>Incorporating chiral elements in host–guest systems currently attracts much attention because of the major impact such structures may have in a wide range of applications, from pharmaceuticals to materials science and beyond. Moreover, the development of multi‐responsive and ‐functional systems is highly desirable since they offer numerous benefits. In this context, we describe herein the construction of a metal‐driven self‐assembled cage that associates a chiral truxene‐based ligand and a bis‐ruthenium complex. The maximum separation between both facing chiral units in the assembly is fixed by the intermetallic distance within the lateral bis‐ruthenium complex (8.4 Å). The resulting chiral cavity was shown to encapsulate polyaromatic guest molecules, but also to afford a chiral triply interlocked [2]catenane structure. The formation of the latter occurs at high concentration, while its disassembly could be achieved by the addition of a planar achiral molecule. Interestingly the planar achiral molecule exhibits induced circular dichroism signature when trapped within the chiral cavity, thus demonstrating the ability of the cage to induce supramolecular chirogenesis.</jats:p>