| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Wang, Dong
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Engineered Anchor Peptide LCI with a Cobalt Cofactor Enhances Oxidation Efficiency of Polystyrene Microparticlescitations
- 2024Hydrogen diffusivity in X65 pipeline steel: Desorption and permeation studiescitations
- 2024Low-temperature process design for inversion mode n-channel thin-film-transistor on polycrystalline Ge formed by solid-phase crystallizationcitations
- 2024Controllable Si oxidation mediated by annealing temperature and atmosphere
- 2024Safe pipelines for hydrogen transportcitations
- 2024Integration of Multijunction Absorbers and Catalysts for Efficient Solar‐Driven Artificial Leaf Structures: A Physical and Materials Science Perspectivecitations
- 2023Gold nanosponges: fascinating optical properties of a unique disorder-dominated systemcitations
- 2022A dual functional chondro-inductive chitosan thermogel with high shear modulus and sustained drug release for cartilage tissue engineeringcitations
- 2022Controllable Si oxidation mediated by annealing temperature and atmospherecitations
- 2022Thin film nanostructuring at oblique angles by substrate patterning
- 2021Rapid fabrication and interface structure of highly faceted epitaxial Ni-Au solid solution nanoparticles on sapphirecitations
- 2019Investigation of a surface mounted pm machine concept with 3d-flux paths, modular stator and amorphous materialcitations
- 2018The effect of in-situ hydrogen plasma charging on the hydrogen embrittlement susceptibility of DP and TRIP steel
- 2016Solid-state dewetting of single- and bilayer Au-W thin films: unraveling the role of individual layer thickness, stacking sequence and oxidation on morphology evolutioncitations
- 2014A highly active and magnetically recoverable tris(triazolyl)-CuI catalyst for alkyne-azide cycloaddition reactionscitations
- 2013Nuclear resonance vibrational spectroscopic and computational study of high-valent diiron complexes relevant to enzyme intermediates.citations
- 2005Polymerization and carbonization of high internal phase emulsionscitations
Places of action
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article
Engineered Anchor Peptide LCI with a Cobalt Cofactor Enhances Oxidation Efficiency of Polystyrene Microparticles
Abstract
<jats:title>Abstract</jats:title><jats:p>A typical component of polymer waste is polystyrene (PS) used in numerous applications, but degraded only slowly in the environment due to its hydrophobic properties. To increase the reactivity of polystyrene, polar groups need to be introduced. Here, biohybrid catalysts based on the engineered anchor peptide LCI_F16C are presented, which are capable of attaching to polystyrene microparticles and hydroxylating benzylic C−H bonds in polystyrene microparticles using commercially available oxone as oxidant. LCI peptides achieve a dense surface coverage of PS through monolayer formation within minutes in aqueous solutions at ambient temperature. The catalytically active cobalt cofactor <jats:bold>Co</jats:bold>‐<jats:bold>L1</jats:bold> or <jats:bold>Co</jats:bold>‐<jats:bold>L2</jats:bold> with a modified <jats:italic>NNNN</jats:italic> macrocyclic TACD ligand (TACD=1,4,7,10‐tetraazacyclododecane) is covalently bound to the anchor peptide LCI through a maleimide linker. Compared to the free cofactors, a 12‐ to 15‐fold improvement in catalytic activity using biohybrid catalysts based on LCI_F16C was observed.</jats:p>