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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zhang, Heng
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2024Strong Substrate Influence on Atomic Structure and Properties of Epitaxial VO 2 Thin Filmscitations
- 2024Strong substrate influence on atomic structure and properties of epitaxial VO2 thin filmscitations
- 2023Strong substrate influence on atomic structure and properties of epitaxial VO2 thin filmscitations
- 2023Effects of Intermixing in Sb2Te3/Ge1+xTe Multilayers on the Thermoelectric Power Factorcitations
- 2023Dislocations and a domains coupling in PbTiO3 thin filmscitations
- 2023N=8 Armchair Graphene Nanoribbons: Solution Synthesis and High Charge Carrier Mobility**
- 2023N=8 armchair graphene nanoribbonscitations
- 2022Nanostructure and thermal power of highly-textured and single-crystal-like Bi2Te3 thin filmscitations
- 2022Nanostructure and thermal power of highly-textured and single-crystal-like Bi2Te3 thin filmscitations
- 2021Pulsed laser deposited stoichiometric GaSb films for optoelectronic and phase change memory applicationscitations
- 2021Pulsed laser deposited stoichiometric GaSb films for optoelectronic and phase change memory applicationscitations
- 2020Differences in Sb2Te3 growth by pulsed laser and sputter depositioncitations
- 2020Frequency-domain study of nonthermal gigahertz phonons reveals Fano coupling to charge carrierscitations
- 2019Fluorine‐Free Noble Salt Anion for High‐Performance All‐Solid‐State Lithium–Sulfur Batteriescitations
- 2017Vibrational spectroscopic studies combined with viscosity analysis and VTF calculation for hybrid polymer electrolytescitations
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article
N=8 armchair graphene nanoribbons
Abstract
<p>Structurally defined graphene nanoribbons (GNRs) have emerged as promising candidates for nanoelectronic devices. Low band gap (<1 eV) GNRs are particularly important when considering the Schottky barrier in device performance. Here, we demonstrate the first solution synthesis of 8-AGNRs through a carefully designed arylated polynaphthalene precursor. The efficiency of the oxidative cyclodehydrogenation of the tailor-made polymer precursor into 8-AGNRs was validated by FT-IR, Raman, and UV/Vis-near-infrared (NIR) absorption spectroscopy, and further supported by the synthesis of naphtho[1,2,3,4-<i>ghi</i>]perylene derivatives (<b>1</b> and <b>2</b>) as subunits of <b>8-AGNR</b>, with a width of 0.86 nm as suggested by the X-ray single crystal analysis. Low-temperature scanning tunneling microscopy (STM) and solid-state NMR analyses provided further structural support for <b>8-AGNR</b>. The resulting <b>8-AGNR</b> exhibited a remarkable NIR absorption extending up to ∼2400 nm, corresponding to an optical band gap as low as ∼0.52 eV. Moreover, optical-pump TeraHertz-probe spectroscopy revealed charge-carrier mobility in the dc limit of ∼270 cm<sup>2</sup> V<sup>−1</sup> s<sup>−1</sup> for the <b>8-AGNR</b>.</p>