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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Feng, Xinliang
European Commission
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (58/58 displayed)
- 2024Impact of Thermal Annealing on the Dissolution of Semiconducting Polymer Thin Filmscitations
- 2024Venice’s macroalgae-derived active material for aqueous, organic, and solid-state supercapacitorscitations
- 2024Coexistence of Redox‐Active Metal and Ligand Sites in Copper‐based 2D Conjugated Metal‐Organic Frameworks for Battery‐Supercapacitor hybrid systemscitations
- 2024Mimicking on-water surface synthesis through micellar interfacescitations
- 2023Tailoring the Morphology of a Diketopyrrolopyrrole-based Polymer as Films or Wires for High-Performance OFETs using Solution Shearingcitations
- 2023On-water surface synthesis of electronically coupled 2D polyimide-MoS2 van der Waals heterostructurecitations
- 2023On-surface synthesis and characterization of teranthene and hexanthene: ultrashort graphene nanoribbons with mixed armchair and zigzag edgescitations
- 2023Curved graphene nanoribbons derived from tetrahydropyrene-based polyphenylenes via one-pot K-region oxidation and Scholl cyclizationcitations
- 2023Tunable Crystallinity and Electron Conduction in Wavy 2D Conjugated Metal–Organic Frameworks via Halogen Substitutioncitations
- 2023Hybrid aeromaterials for enhanced and rapid volumetric photothermal response
- 2023Piezo‐Phototronic In2Se3 Nanosheets as a Material Platform for Printable Electronics toward Multifunctional Sensing Applicationscitations
- 2023Near IR Bandgap Semiconducting 2D Conjugated Metal‐Organic Framework with Rhombic Lattice and High Mobilitycitations
- 2022Combination of Knoevenagel Polycondensation and Water-Assisted Dynamic Michael-Addition-Elimination for the Synthesis of Vinylene-Linked 2D Covalent Organic Frameworkscitations
- 2022Combination of Knoevenagel Polycondensation and Water-Assisted Dynamic Michael-Addition-Elimination for the Synthesis of Vinylene-Linked 2D Covalent Organic Frameworkscitations
- 2021Microengineered Hollow Graphene Tube Systems Generate Conductive Hydrogels with Extremely Low Filler Concentrationcitations
- 2021Multiscale Modeling Strategy of 2D Covalent Organic Frameworks Confined at an Air–Water Interfacecitations
- 2020Polycyclic aromatic chains on metals and insulating layers by repetitive [3+2] cycloadditionscitations
- 2020Polycyclic aromatic chains on metals and insulating layers by repetitive [3+2] cycloadditionscitations
- 2020Near–atomic-scale observation ofgrain boundaries inalayer-stacked two-dimensional polymercitations
- 2020Production and processing of graphene and related materials
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materials
- 2020Wetting Properties of Graphene Aerogelscitations
- 2020Two-Dimensional Boronate Ester Covalent Organic Framework Thin Films with Large Single Crystalline Domains for a Neuromorphic Memory Devicecitations
- 2020Highly selective and ultra-low power consumption metal oxide based hydrogen gas sensor employing graphene oxide as molecular sievecitations
- 2020Highly selective and ultra-low power consumption metal oxide based hydrogen gas sensor employing graphene oxide as molecular sievecitations
- 2020Highly crystalline and semiconducting imine‐based two‐dimensional polymers enabled by interfacial synthesis
- 2019Engineering crystalline quasi-two-dimensional polyaniline thin film with enhanced electrical and chemiresistive sensing performancescitations
- 2019On-surface synthesis of nitrogen-doped nanographenes with 5–7 membered ringscitations
- 2019Beyond Activated Carbon: Graphite‐Cathode‐Derived Li‐Ion Pseudocapacitors with High Energy and High Power Densitiescitations
- 2019Electrochemically Exfoliated High-Quality 2H-MoS<sub>2</sub> for Multiflake Thin Film Flexible Biosensorscitations
- 2019On‐surface synthesis and characterization of acene‐based nanoribbons incorporating four‐membered ringscitations
- 2019Topological defect-induced magnetism in a nanographenecitations
- 2019Fully sp2‐Carbon‐Linked Crystalline Two‐Dimensional Conjugated Polymers: Insight into 2D Poly(phenylenecyanovinylene) Formation and its Optoelectronic Propertiescitations
- 2018Engineering of robust topological quantum phases in graphene nanoribbonscitations
- 2018The mechanochemical Scholl reaction – a solvent-free and versatile graphitization toolcitations
- 2017Persulfurated Coronene: A New Generation of "Sulflower"citations
- 2017A Stable Saddle-Shaped Polycyclic Hydrocarbon with an Open-Shell Singlet Ground Statecitations
- 2017Revealing the electronic structure of silicon intercalated armchair graphene nanoribbons by scanning tunneling spectroscopycitations
- 2017Coordination Polymer Framework Based On-Chip Micro-Supercapacitors with AC Line-Filtering Performancecitations
- 2017Polycyclic heteroaromatic hydrocarbons containing a benzoisoindole corecitations
- 2017Monitoring the on-surface synthesis of graphene nanoribbons by mass spectrometrycitations
- 2016Synthesis of Graphene Nanoribbons by Ambient-Pressure Chemical Vapor Deposition and Device Integrationcitations
- 2016On-surface synthesis of graphene nanoribbons with zigzag edge topologycitations
- 2016Synthesis of NBN-Type Zigzag-Edged Polycyclic Aromatic Hydrocarbons: 1,9-Diaza-9a-boraphenalene as a Structural Motifcitations
- 2015Toward cove-edged low band gap graphene nanoribbonscitations
- 2014Squeezing, Then Stacking: From Breathing Pores to Three-Dimensional Ionic Self-Assembly under Electrochemical Controlcitations
- 2013Termini of bottom-up fabricated graphene nanoribbonscitations
- 2012Nitrogen-Doped Graphene and Its Iron-Based Composite As Efficient Electrocatalysts for Oxygen Reduction Reactioncitations
- 2010Self-assembling thiophene dendrimers with a hexa-peri-hexabenzocoronene core- synthesis, characterization and performance in bulk heterojunction solar cellscitations
- 2009Self-assembling thiophene dendrimers with a hexa-peri-hexabenzocoronene core- synthesis, characterization and performance in bulk heterojunction solar cells
- 2008Molecular clusters in two-dimensional surface-confined nanoporous molecular networks: structure, rigidity, and dynamicscitations
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article
Near IR Bandgap Semiconducting 2D Conjugated Metal‐Organic Framework with Rhombic Lattice and High Mobility
Abstract
<jats:title>Abstract</jats:title><jats:p>Two‐dimensional conjugated metal–organic frameworks (2D <jats:italic>c‐</jats:italic>MOFs) are emerging as a unique class of electronic materials. However, 2D <jats:italic>c</jats:italic>‐MOFs with band gaps in the Vis‐NIR and high charge carrier mobility are rare. Most of the reported conducting 2D <jats:italic>c‐</jats:italic>MOFs are metallic (i.e. gapless), which largely limits their use in logic devices. Herein, we design a phenanthrotriphenylene‐based, D<jats:sub>2h</jats:sub>‐symmetric π‐extended ligand (<jats:bold>OHPTP</jats:bold>), and synthesize the first rhombic 2D <jats:italic>c‐</jats:italic>MOF single crystals (<jats:bold>Cu<jats:sub>2</jats:sub>(OHPTP)</jats:bold>). The continuous rotation electron diffraction (cRED) analysis unveils the orthorhombic crystal structure at the atomic level with a unique slipped AA stacking. The <jats:bold>Cu<jats:sub>2</jats:sub>(OHPTP)</jats:bold> is a <jats:italic>p</jats:italic>‐type semiconductor with an indirect band gap of ≈0.50 eV and exhibits high electrical conductivity of 0.10 S cm<jats:sup>−1</jats:sup> and high charge carrier mobility of ≈10.0 cm<jats:sup>2</jats:sup> V<jats:sup>−1</jats:sup> s<jats:sup>−1</jats:sup>. Theoretical calculations underline the predominant role of the out‐of‐plane charge transport in this semiquinone‐based 2D <jats:italic>c‐</jats:italic>MOF.</jats:p>