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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Chen, Yen-Ting
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2023Scalable Synthesis of Multi‐Metal Electrocatalyst Powders and Electrodes and their Application for Oxygen Evolution and Water Splittingcitations
- 2022Nonaqueous emulsion polycondensation enabled by a self-assembled cage-like surfactant
- 2021Coordination cage-based emulsifiers: templated formation of metal oxide microcapsules monitored by in situ LC-TEM
- 2019Towards mechanistic understanding of liquid-phase cinnamyl alcohol oxidation with (it tert)-butyl hydroperoxide over noble-metal-free LaCo(_{1–x})Fe(_x)O(_3) perovskites
- 2018Discovery of a multinary noble metal-free oxygen reduction catalystcitations
- 2016Correlative theoretical and experimental investigation of the formation of AIYB(14) and competing phasescitations
Places of action
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article
Scalable Synthesis of Multi‐Metal Electrocatalyst Powders and Electrodes and their Application for Oxygen Evolution and Water Splitting
Abstract
<jats:title>Abstract</jats:title><jats:p>Multi‐metal electrocatalysts provide nearly unlimited catalytic possibilities arising from synergistic element interactions. We propose a polymer/metal precursor spraying technique that can easily be adapted to produce a large variety of compositional different multi‐metal catalyst materials. To demonstrate this, 11 catalysts were synthesized, characterized, and investigated for the oxygen evolution reaction (OER). Further investigation of the most active OER catalyst, namely CoNiFeMoCr, revealed a polycrystalline structure, and operando Raman measurements indicate that multiple active sites are participating in the reaction. Moreover, Ni foam‐supported CoNiFeMoCr electrodes were developed and applied for water splitting in flow‐through electrolysis cells with electrolyte gaps and in zero‐gap membrane electrode assembly (MEA) configurations. The proposed alkaline MEA‐type electrolyzers reached up to 3 A cm<jats:sup>−2</jats:sup>, and 24 h measurements demonstrated no loss of current density of 1 A cm<jats:sup>−2</jats:sup>.</jats:p>