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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Li, Tao
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2023Structural, optical, and thermal properties of BN thin films grown on diamond via pulsed laser depositioncitations
- 2023Structural, optical, and thermal properties of BN thin films grown on diamond via pulsed laser deposition
- 2022A Carboranyl Electrolyte Enabling Highly Reversible Sodium Metal Anodes via a “Fluorine‐Free” SEIcitations
- 2020Investigation of flame retarded polypropylene by high-speed planar laser-induced fluorescence of OH radicals combined with a thermal decomposition analysiscitations
- 2020Spacer-defined intrinsic multiple patterningcitations
- 2018Structure-function correlative microscopy of peritubular and intertubular dentinecitations
- 2018Transition to Superwetting for a Nanostructured Surface
- 2018Transition to Superwetting for a Nanostructured Surface
- 2018Modeling salinity effect on rice growth and rice yield with ORYZA v3 and APSIM-Oryzacitations
- 2018Mapping the transition to superwetting state for nanotextured surfaces templated from block-copolymer self-assemblycitations
- 2018Mapping the transition to superwetting state for nanotextured surfaces templated from block-copolymer self-assemblycitations
- 2018Mapping the transition to superwetting state for nanotextured surfaces templated from block-copolymer self-assemblycitations
- 2016Understanding nature’s residual strain engineering at the human dentine-enamel junction interfacecitations
- 2016Wafer-Scale Nanopillars Derived from Block Copolymer Lithography for Surface-Enhanced Raman Spectroscopycitations
- 2016Effects of coating spherical iron oxide nanoparticlescitations
- 2015Fast & scalable pattern transfer via block copolymer nanolithographycitations
- 2015Nanoporous gyroid TiO2 and SnO2 by melt infiltration of block copolymer templatescitations
- 2015Nanoporous gyroid TiO 2 and SnO 2 by melt infiltration of block copolymer templatescitations
Places of action
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article
A Carboranyl Electrolyte Enabling Highly Reversible Sodium Metal Anodes via a “Fluorine‐Free” SEI
Abstract
<jats:title>Abstract</jats:title><jats:p>Realization of practical sodium metal batteries (SMBs) is hindered due to lack of compatible electrolyte components, dendrite propagation, and poor understanding of anodic interphasial chemistries. Chemically robust liquid electrolytes that facilitate both favorable sodium metal deposition and a stable solid‐electrolyte interphase (SEI) are ideal to enable sodium metal and anode‐free cells. Herein we present advanced characterization of a novel fluorine‐free electrolyte utilizing the [HCB<jats:sub>11</jats:sub>H<jats:sub>11</jats:sub>]<jats:sup>1−</jats:sup> anion. Symmetrical Na cells operated with this electrolyte exhibit a remarkably low overpotential of 0.032 V at a current density of 2.0 mA cm<jats:sup>−2</jats:sup> and a high coulombic efficiency of 99.5 % in half‐cell configurations. Surface characterization of electrodes post‐operation reveals the absence of dendritic sodium nucleation and a surprisingly stable fluorine‐free SEI. Furthermore, weak ion‐pairing is identified as key towards the successful development of fluorine‐free sodium electrolytes.</jats:p>