| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Guillaume, Sophie M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2024Metal-catalyzed stereoselective ring-opening polymerization of functional β-lactones: methylene-alkoxy-fluorinated polyhydroxyalkanoates unveil the role of non-covalent interactionscitations
- 2024Ring-opening (co)polymerization of chiral seven-membered lactones mediated by achiral yttrium catalysts: Insights into the catalyst stereocontrol by mass spectrometrycitations
- 2024Phosphorus-containing stereocontrolled polyhydroxyalkanoates by yttrium-mediated ring-opening copolymerization of β-lactonescitations
- 2023Chemistry that allows plastic recyclingcitations
- 2022Polythioesters Prepared by Ring-Opening Polymerization of Cyclic Thioesters and Related Monomerscitations
- 2022Upgrading Toughness and Glass Transition Temperature of Polydicyclopentadiene Upon Addition of Styrene-Ethylene-Butylene-Styrene Thermoplastic Elastomercitations
- 2022Tacticity Control of Cyclic Poly(3-Thiobutyrate) Prepared by Ring-Opening Polymerization of Racemic beta-Thiobutyrolactonecitations
- 2020Ring-opening (co)polymerization of six-membered substituted delta-valerolactones with alkali metal alkoxidescitations
- 2020Recent Advances in Metal-Mediated Stereoselective Ring-Opening Polymerization of Functional Cyclic Esters towards Well-defined Poly(hydroxy acid)s: From Stereoselectivity to Sequence‐Controlcitations
- 2018Evaluation of band-selective HSQC and HMBC Methodological validation on the cyclosporin cyclic peptide and application for poly(3-hydroxyalkanoate)s stereoregularity determinationcitations
- 2017Tuning the properties of α,ω-bis(trialkoxysilyl) telechelic copolyolefins from ruthenium-catalyzed chain-transfer ring-opening metathesis polymerization (ROMP)citations
- 2016Poly(trimethylene carbonate)/Poly(malic acid) Amphiphilic Diblock Copolymers as Biocompatible Nanoparticlescitations
- 2016New Linear and Star-Shaped Thermogelling Poly([ R ]-3-hydroxybutyrate) Copolymerscitations
- 2015Syndioselective ring-opening polymerization and copolymerization of trans-1,4-cyclohexadiene carbonate mediated by achiral metal- and organo-catalystscitations
- 2015Beyond Stereoselectivity, Switchable Catalysis: Some of the Last Frontier Challenges in Ring-Opening Polymerization of Cyclic Esterscitations
- 2015Ethylene carbonate/cyclic ester random copolymers synthesized by ring-opening polymerizationcitations
- 2014From Syndiotactic Homopolymers to Chemically Tunable Alternating Copolymers: Highly Active Yttrium Complexes for Stereoselective Ring-Opening Polymerization of β-Malolactonatescitations
- 2014Synthesis and polymerization of cyclobutenyl-functionalized polylactide and polycaprolactone: a consecutive ROP/ROMP route towards poly(1,4-butadiene)-g-polyesterscitations
- 2014From glycidyl carbonate to hydroxyurethane sidegroups in alternating fluorinated copolymerscitations
- 2013Organometallic strontium borohydrides - synthesis, catalytic studies, and DFT calculationscitations
- 2013Poly(hydroxyalkanoate) Block or Random Copolymers of β-Butyrolactone and Benzyl β-Malolactone: A Matter of Catalytic Tuning.citations
Places of action
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article
Tacticity Control of Cyclic Poly(3-Thiobutyrate) Prepared by Ring-Opening Polymerization of Racemic beta-Thiobutyrolactone
Abstract
We report here on the ring-opening polymerization (ROP) of racemic beta-thiobutyrolactone (rac-TBL), as the first chemical synthesis of poly(3-thiobutyrolactone) (P3TB), the thioester analogue of the ubiquitous poly(3-hydroxybutyrate) (P3HB). The ROP reactions proceed very fast (TOF >12 000 h(-1) at r.t.) in the presence of various metal-based catalysts. Remarkably, catalyst systems based on non-chiral yttrium complexes stabilized by tetradentate amino alkoxy- or diamino-bis(phenolate) ligands {ONXOR1,R2}(2-) (X=O, N) provide access to cyclic P3TB with either high isoselectivity (P-m up to 0.90) or high syndiotactic bias (P-r up to 0.70). The stereoselectivity can be controlled by manipulation of the substituents on the ligand platform and adequate choice of the reaction solvent and temperature as well. The cyclic polymer topology is evidenced by MALDI-ToF MS, NMR and TGA. Highly isotactic cyclic P3TB is a semi-crystalline material as revealed by DSC.