| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Aromí, Guillem
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Energy exchange between Nd 3+ and Er 3+ centers within molecular complexescitations
- 2022Unravelling of a [High Spin—Low Spin] ↔ [Low Spin—High Spin] Equilibrium in Spin‐Crossover Iron(II) Dinuclear Helicates Using Paramagnetic NMR Spectroscopycitations
- 2020Pathway selection as a tool for crystal defect engineering: A case study with a functional coordination polymercitations
- 2020Pathway selection as a tool for crystal defect engineering: A case study with a functional coordination polymercitations
- 2020Allosteric spin crossover induced by ligand-based molecular alloyingcitations
- 2018Encapsulation of a CrIII single-ion magnet within an feII spin-crossover supramolecular hostcitations
- 2017Molecules designed to contain two weakly coupled spins with a photoswitchable spacercitations
- 2014Characterization of a robust Co II fluorescent complex deposited intact on HOPGcitations
- 2012Molecular [(Fe 3)-(Fe 3)] and [(Fe 4)- (Fe 4)] coordination cluster pairs as single or composite arrayscitations
- 2010Synthesis of a novel heptacoordinated Fe(III) dinuclear complex: experimental and theoretical study of the magnetic propertiescitations
Places of action
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article
Unravelling of a [High Spin—Low Spin] ↔ [Low Spin—High Spin] Equilibrium in Spin‐Crossover Iron(II) Dinuclear Helicates Using Paramagnetic NMR Spectroscopy
Abstract
<jats:title>Abstract</jats:title><jats:p>Spin‐crossover between high‐spin (HS) and low‐spin (LS) states of selected transition metal ions in polynuclear and polymeric compounds is behind their use as multistep switchable materials in breakthrough electronic and spintronic devices. We report the first successful attempt to observe the dynamics of a rarely found broken‐symmetry spin state in binuclear complexes, which mixes the states [HS‐LS] and [LS‐HS] on a millisecond timescale. The slow exchange between these two states, which was identified by paramagnetic NMR spectroscopy in solutions of two spin‐crossover iron(II) binuclear helicates that are amenable to molecular design, opens a path to double quantum dot cellular automata for information storage and processing.</jats:p>