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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Pomjakushina, Ekaterina
European Commission
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Cobalt-free layered perovskites RBaCuFeO 5+ δ (R = 4f lanthanide) as electrocatalysts for the oxygen evolution reactioncitations
- 2023Spin-orbit control of antiferromagnetic domains without a Zeeman coupling
- 2022Universal spin-glass behaviour in bulk LaNiO2, PrNiO2 and NdNiO2
- 2021Correlation between Oxygen Vacancies and Oxygen Evolution Reaction Activity for a Model Electrode: PrBaCo2O5+δ
- 2021Correlation between Oxygen Vacancies and Oxygen Evolution Reaction Activity for a Model Electrode: PrBaCo<sub>2</sub>O<sub>5+<i>δ</i></sub>citations
- 2021Interdependent scaling of long-range oxygen and magnetic ordering in nonstoichiometric Nd$_2$NiO$_{4.10}$citations
- 2020Electron-phonon-driven three-dimensional metallicity in an insulating cupratecitations
- 2020Electron-phonon-driven three-dimensional metallicity in an insulating cupratecitations
- 2020Electron-phonon-driven three-dimensional metallicity in an insulating cupratecitations
- 2020Magnetism and anomalous transport in the Weyl semimetal PrAlGe: possible route to axial gauge fieldscitations
- 2020Anisotropic character of the metal-to-metal transition in Pr4Ni3O10citations
- 2019Structural disorder and magnetic correlations driven by oxygen doping in Nd_{2}NiO_{4+δ} ( δ ∼ 0.11 )citations
- 2019Nodeless superconductivity and its evolution with pressure in the layered dirac semimetal $2M-WS_2$
- 2019Laue three dimensional neutron diffractioncitations
- 2019Nodeless superconductivity and its evolution with pressure in the layered dirac semimetal 2M-WS2citations
- 2015Wet milling versus co-precipitation in magnetite ferrofluid preparationcitations
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article
Correlation between Oxygen Vacancies and Oxygen Evolution Reaction Activity for a Model Electrode: PrBaCo<sub>2</sub>O<sub>5+<i>δ</i></sub>
Abstract
<jats:title>Abstract</jats:title><jats:p>The role of the perovskite lattice oxygen in the oxygen evolution reaction (OER) is systematically studied in the PrBaCo<jats:sub>2</jats:sub>O<jats:sub>5+δ</jats:sub> family. The reduced number of physical/chemical variables combined with in‐depth characterizations such as neutron dif‐fraction, O K‐edge X‐ray absorption spectroscopy (XAS), electron energy loss spectroscopy (EELS), magnetization and scanning transmission electron microscopy (STEM) studies, helps investigating the complex correlation between OER activity and a single perovskite property, such as the oxygen content. Larger amount of oxygen vacancies appears to facilitate the OER, possibly contributing to the mechanism involving the oxidation of lattice oxygen, i.e., the lattice oxygen evolution reaction (LOER). Furthermore, not only the number of vacancies but also their local arrangement in the perovskite lattice influences the OER activity, with a clear drop for the more stable, ordered stoichiometry.</jats:p>