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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Müller, Elisabeth
Paul Scherrer Institute
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 20233D-Imaging of synapses in neuronal tissues with synchrotron X-ray ptychographycitations
- 2023Understanding the microstructure of a core–shell anode catalyst layer for polymer electrolyte water electrolysiscitations
- 2021Correlation between Oxygen Vacancies and Oxygen Evolution Reaction Activity for a Model Electrode: PrBaCo2O5+δ
- 2021Correlation between Oxygen Vacancies and Oxygen Evolution Reaction Activity for a Model Electrode: PrBaCo<sub>2</sub>O<sub>5+<i>δ</i></sub>citations
- 2019Ferroelectric Self-Poling in GeTe Films and Crystalscitations
- 2019Ferroelectric Self-Poling in GeTe Films and Crystals
- 2018Unsupported Pt-Ni Aerogels with Enhanced High Current Performance and Durability in Fuel Cell Cathodescitations
- 2017Top-down method to introduce ultra-high elastic straincitations
- 2004Annealing studies of high Ge composition Si/SiGe multilayerscitations
Places of action
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article
Correlation between Oxygen Vacancies and Oxygen Evolution Reaction Activity for a Model Electrode: PrBaCo<sub>2</sub>O<sub>5+<i>δ</i></sub>
Abstract
<jats:title>Abstract</jats:title><jats:p>The role of the perovskite lattice oxygen in the oxygen evolution reaction (OER) is systematically studied in the PrBaCo<jats:sub>2</jats:sub>O<jats:sub>5+δ</jats:sub> family. The reduced number of physical/chemical variables combined with in‐depth characterizations such as neutron dif‐fraction, O K‐edge X‐ray absorption spectroscopy (XAS), electron energy loss spectroscopy (EELS), magnetization and scanning transmission electron microscopy (STEM) studies, helps investigating the complex correlation between OER activity and a single perovskite property, such as the oxygen content. Larger amount of oxygen vacancies appears to facilitate the OER, possibly contributing to the mechanism involving the oxidation of lattice oxygen, i.e., the lattice oxygen evolution reaction (LOER). Furthermore, not only the number of vacancies but also their local arrangement in the perovskite lattice influences the OER activity, with a clear drop for the more stable, ordered stoichiometry.</jats:p>