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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hübner, René
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (25/25 displayed)
- 2023Room-temperature extended short-wave infrared GeSn photodetectors realized by ion beam techniquescitations
- 2023Structural investigations of Au–Ni aerogels: morphology and element distributioncitations
- 2023Bottom-up fabrication of FeSb2 nanowires on crystalline GaAs substrates with ion-induced pre-patterning
- 2022Defect Nanostructure and its Impact on Magnetism of α-Cr2O3 thin filmscitations
- 2022Flexomagnetism and vertically graded Néel temperature of antiferromagnetic Cr2O3 thin films
- 2022Homogenization and short-range chemical ordering of Co–Pt alloys driven by the grain boundary migration mechanismcitations
- 2022Band-gap and strain engineering in GeSn alloys using post-growth pulsed laser melting
- 2022Self-Supported Three-Dimensional Quantum Dot Aerogels as a Promising Photocatalyst for CO2 Reduction
- 2021Controlled Silicidation of Silicon Nanowires Using Flash Lamp Annealingcitations
- 2020Increasing the Diversity and Understanding of Semiconductor Nanoplatelets by Colloidal Atomic Layer Deposition
- 2020Formation of Thin NiGe Films by Magnetron Sputtering and Flash Lamp Annealingcitations
- 2020Directionality of metal-induced crystallization and layer exchange in amorphous carbon/nickel thin film stackscitations
- 2020Tunable magnetic vortex dynamics in ion-implanted permalloy diskscitations
- 2019Specific ion effects directed noble metal aerogels: Versatile manipulation for electrocatalysis and beyondcitations
- 2019Structure-property relationship of Co 2 MnSi thin films in response to He + -irradiation
- 2018Percolated Si:SiO2 Nanocomposites: Oven- vs. Millisecond Laser-Induced Crystallization of SiOx Thin Filmscitations
- 2018Nematicity of correlated systems driven by anisotropic chemical phase separationcitations
- 2018Core–Shell Structuring of Pure Metallic Aerogels towards Highly Efficient Platinum Utilization for the Oxygen Reduction Reactioncitations
- 2017Interplay between localization and magnetism in (Ga,Mn)As and (In,Mn)As
- 2017Purely antiferromagnetic magnetoelectric random access memory
- 2016Bonding structure and morphology of chromium oxide films grown by pulsed-DC reactive magnetron sputter depositioncitations
- 2016Carbon : nickel nanocomposite templates - predefined stable catalysts for diameter-controlled growth of single-walled carbon nanotubescitations
- 2013Forming-free resistive switching in multiferroic BiFeO3 thin films with enhanced nanoscale shuntscitations
- 2005Focussing and defocussing effects at radio frequency glow discharge optical emission spectroscopy analyses of thin films with partly nonconductive componentscitations
- 2002Crystallisation of caesium borosilicate glasses with approximate boroleucite compositioncitations
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article
Core–Shell Structuring of Pure Metallic Aerogels towards Highly Efficient Platinum Utilization for the Oxygen Reduction Reaction
Abstract
<jats:title>Abstract</jats:title><jats:p>The development of core–shell structures remains a fundamental challenge for pure metallic aerogels. Here we report the synthesis of Pd<jats:sub><jats:italic>x</jats:italic></jats:sub>Au‐Pt core–shell aerogels composed of an ultrathin Pt shell and a composition‐tunable Pd<jats:sub><jats:italic>x</jats:italic></jats:sub>Au alloy core. The universality of this strategy ensures the extension of core compositions to Pd transition‐metal alloys. The core–shell aerogels exhibited largely improved Pt utilization efficiencies for the oxygen reduction reaction and their activities show a volcano‐type relationship as a function of the lattice parameter of the core substrate. The maximum mass and specific activities are 5.25 A mg<jats:sub>Pt</jats:sub><jats:sup>−1</jats:sup> and 2.53 mA cm<jats:sup>−2</jats:sup>, which are 18.7 and 4.1 times higher than those of Pt/C, respectively, demonstrating the superiority of the core–shell metallic aerogels. The proposed core‐based activity descriptor provides a new possible strategy for the design of future core–shell electrocatalysts.</jats:p>