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Freudenberg, Jan
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Publications (4/4 displayed)
- 2024Breaking Strong Alkynyl-Phenyl Bonds: Poly(para-phenylene ethynylene)s under Mechanical Stress [data]
- 2022Crosslinking Super Yellow to produce super OLEDs: Crosslinking with azides enables improved performance
- 20195,7,12,14‐Tetrafunctionalized 6,13‐Diazapentacenescitations
- 2015Reverse Engineering of Conjugated Microporous Polymers: Defect Structures of Tetrakis(4‐ethynylphenyl)stannane Networkscitations
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article
Reverse Engineering of Conjugated Microporous Polymers: Defect Structures of Tetrakis(4‐ethynylphenyl)stannane Networks
Abstract
<jats:title>Abstract</jats:title><jats:p>Two different conjugated microporous polymers (CMPs) based on tetrakis(4‐ethynylphenyl)stannane as the repeating unit were synthesized and their BET surfaces and thermal properties were investigated. The first direct method to elucidate the molecular structure of the organic linkers between the tin centers by digestion of the CMP is described. Selective cleavage of the tin–carbon bonds with chloroacetic acid afforded the isolated bridging units and provided insight into the surprisingly varied chemical composition of these networks.</jats:p>