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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Renggli, Kasper
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2016Protein cages and synthetic polymerscitations
- 2014A chaperonin as protein nanoreactor for atom-transfer radical polymerizationcitations
- 2013Combining polymers with the functionality of proteinscitations
- 2013Combining Polymers with the Functionality of Proteins: New Concepts for Atom Transfer Radical Polymerization, Nanoreactors and Damage Self-reporting Materialscitations
- 2013Hemoglobin and red blood cells catalyze atom transfer radical polymerizationcitations
- 2012ATRPasescitations
- 2011Selective and responsive nanoreactorscitations
- 2011Horseradish peroxidase as a catalyst for atom transfer radical polymerizationcitations
Places of action
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article
A chaperonin as protein nanoreactor for atom-transfer radical polymerization
Abstract
<p>The group II chaperonin thermosome (THS) from the archaea Thermoplasma acidophilum is reported as nanoreactor for atom-transfer radical polymerization (ATRP). A copper catalyst was entrapped into the THS to confine the polymerization into this protein cage. THS possesses pores that are wide enough to release polymers into solution. The nanoreactor favorably influenced the polymerization of Nisopropyl acrylamide and poly(ethylene glycol)methylether acrylate. Narrowly dispersed polymers with polydispersity indices (PDIs) down to 1.06 were obtained in the protein nanoreactor, while control reactions with a globular protein- catalyst conjugate only yielded polymers with PDIs above 1.84.</p>