| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Amal, Rose
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Triggering C‒N Coupling on Metal Oxide Nanocomposite for the Electrochemical Reduction of CO<sub>2</sub> and NO<i><sub>x</sub></i>⁻ to Formamidecitations
- 2021Integrating low-cost earth-abundant co-catalysts with encapsulated perovskite solar cells for efficient and stable overall solar water splittingcitations
- 2020Dynamic single-site polysulfide immobilization in long-range disorder Cu-MOFscitations
- 2020Tuning the Selectivity of LaNiO3 Perovskites for CO2 Hydrogenation through Potassium Substitutioncitations
- 2018Multipronged Validation of Oxalate C-C Bond Cleavage Driven by Au-TiO2 Interfacial Charge Transfer Using Operando DRIFTScitations
- 2018Electroreduction of CO2 to CO on a Mesoporous Carbon Catalyst with Progressively Removed Nitrogen Moietiescitations
- 2016Photoelectrochemical water oxidation using a Bi2MoO6/MoO3 heterojunction photoanode synthesised by hydrothermal treatment of an anodised MoO3 thin filmcitations
- 2015Z-schematic water splitting into H2 and O2 using metal sulfide as a hydrogen-evolving photocatalyst and reduced graphene oxide as a solid-state electron mediatorcitations
- 2014Interface-dependent electrochemical behavior of nanostructured manganese (IV) oxide (Mn3O4)citations
- 2012A perspective on fabricating carbon-based nanomaterials by photocatalysis and their applicationscitations
- 2011Semiconductor/reduced graphene oxide nanocomposites derived from photocatalytic reactionscitations
Places of action
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article
Triggering C‒N Coupling on Metal Oxide Nanocomposite for the Electrochemical Reduction of CO<sub>2</sub> and NO<i><sub>x</sub></i>⁻ to Formamide
Abstract
<jats:title>Abstract</jats:title><jats:p>The co‐electroreduction of CO<jats:sub>2</jats:sub> and NO<jats:italic><jats:sub>x</jats:sub></jats:italic>⁻ (NO<jats:sub>3</jats:sub>⁻/NO<jats:sub>2</jats:sub>⁻) to generate formamide (HCONH<jats:sub>2</jats:sub>) offers an opportunity for downstream chemical and polymer manufacturing decarbonization; however, significant challenges lie in the C‒N coupling and the associated low product selectivity. Herein, <jats:italic>p</jats:italic>‐block metal oxides are incorporated in copper oxides to provide more accessible active sites for reactant adsorption and activation, tuning the reaction selectivity toward the formamide production. Through in situ Raman and synchrotron‐based infrared spectroscopy measurements, C─N bond formation is demonstrated in real‐time with the CuO<jats:sub>x</jats:sub>/BiO<jats:sub>x</jats:sub> catalyst, where the C─N bond is detected via a *CHO and *NH<jats:sub>2</jats:sub> intermediates formation, in agreement with the density functional theory calculations. When tested in a flow electrolyzer, a formamide yield rate of 134 ± 11 mmol h<jats:sup>−1</jats:sup> g<jats:sub>cat</jats:sub><jats:sup>−1</jats:sup> is reported, the first report of co‐electroreduction of CO<jats:sub>2</jats:sub> and NO<jats:italic><jats:sub>x</jats:sub></jats:italic>⁻ to formamide beyond conventional H‐cell measurements. These new insights on the C‒N coupling mechanisms and scale‐up capability provide directions for further development of electrocatalysts for the formamide production.</jats:p>