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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wolff, Christian Michael
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Topics
Publications (15/15 displayed)
- 2024Pizza oven processing of organohalide perovskites (POPOP): a simple, versatile and efficient vapor deposition methodcitations
- 2024A Universal Perovskite/C60 Interface Modification via Atomic Layer Deposited Aluminum Oxide for Perovskite Solar Cells and Perovskite–Silicon Tandemscitations
- 2024Alleviating nanostructural phase impurities enhances the optoelectronic properties, device performance and stability of cesium-formamidinium metal–halide perovskitescitations
- 2023Interface passivation for 31.25%-efficient perovskite/silicon tandem solar cellscitations
- 2022Static disorder in lead halide perovskitescitations
- 2019Constructing the Electronic Structure of CH3NH3PbI3 and CH3NH3PbBr3 Perovskite Thin Films from Single-Crystal Band Structure Measurementscitations
- 2019The Role of Bulk and Interface Recombination in High-Efficiency Low-Dimensional Perovskite Solar Cellscitations
- 2019Unraveling the Electronic Properties of Lead Halide Perovskites with Surface Photovoltage in Photoemission Studiescitations
- 2019The impact of energy alignment and interfacial recombination on the internal and external open-circuit voltage of perovskite solar cellscitations
- 2019High open circuit voltages in pin-type perovskite solar cells through strontium additioncitations
- 2017Lead Halide Perovskites as Charge Generation Layers for Electron Mobility Measurement in Organic Semiconductorscitations
- 2017Reduced Interface-Mediated Recombination for High Open-Circuit Voltages in CH3NH3PbI3 Solar Cellscitations
- 2017Efficient light management by textured nanoimprinted layers for perovskite solar cellscitations
- 2017It Takes Two to Tango-Double-Layer Selective Contacts in Perovskite Solar Cells for Improved Device Performance and Reduced Hysteresiscitations
- 2016Charge carrier recombination dynamics in perovskite and polymer solar cellscitations
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article
Pizza oven processing of organohalide perovskites (POPOP): a simple, versatile and efficient vapor deposition method
Abstract
Hybrid vapor deposition is one of the most appealing processes for perovskite photovoltaics fabrication, thanks to its versatile nature. By using sequentially different vapor deposition processes tailored to the inorganic and organic perovskite precursors' peculiarities, this type of process gives access to the full potential of vapor deposition. While vapor deposition of metal halides is well understood and mastered, vapor deposition of organohalide species is much more delicate (degradation of vapors, high vapor pressure, setup-specific constraints). Here, a novel close space sublimation system is reported and in-depth insights on the conversion into perovskite of a metal halide template are provided. In this evolution of the process, the substrate coated with metal halide template and the organohalide source are loaded together in a dedicated holder, then transferred into a vacuum chamber on a heating element already at temperature setpoint. The system enables a simple, fast, low-cost, and easy-to-reproduce organohalide vapor deposition process. The formation of the perovskite in situ and identification different conversion regimes are studied. Furthermore, the influence of the chemical environment and chamber design on the process are discussed. Compositional tuning and additive engineering in the process are processed and fabricate proof of concept photovoltaic devices reaching high fill factors of 80% and 17% power conversion efficiency for a bandgap of 1.63 eV.