People | Locations | Statistics |
---|---|---|
Naji, M. |
| |
Motta, Antonella |
| |
Aletan, Dirar |
| |
Mohamed, Tarek |
| |
Ertürk, Emre |
| |
Taccardi, Nicola |
| |
Kononenko, Denys |
| |
Petrov, R. H. | Madrid |
|
Alshaaer, Mazen | Brussels |
|
Bih, L. |
| |
Casati, R. |
| |
Muller, Hermance |
| |
Kočí, Jan | Prague |
|
Šuljagić, Marija |
| |
Kalteremidou, Kalliopi-Artemi | Brussels |
|
Azam, Siraj |
| |
Ospanova, Alyiya |
| |
Blanpain, Bart |
| |
Ali, M. A. |
| |
Popa, V. |
| |
Rančić, M. |
| |
Ollier, Nadège |
| |
Azevedo, Nuno Monteiro |
| |
Landes, Michael |
| |
Rignanese, Gian-Marco |
|
Blanchard, Didier
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Deciphering the Origin of Interface‐Induced High Li and Na Ion Conductivity in Nanocomposite Solid Electrolytes Using X‐Ray Raman Spectroscopycitations
- 2024Deciphering the Origin of Interface‐Induced High Li and Na Ion Conductivity in Nanocomposite Solid Electrolytes Using X‐Ray Raman Spectroscopycitations
- 2021Small-Angle Neutron Scattering Characterization of SrCl2-ENG Composites for Thermochemical Heat Storagecitations
- 2020Materials for hydrogen-based energy storage – past, recent progress and future outlookcitations
- 2019The influence of silica surface groups on the Li-ion conductivity of LiBH4/SiO2 nanocompositescitations
- 2018Lithium Conductivity and Ions Dynamics in LiBH 4 /SiO 2 Solid-Electrolytes studied by Solid-State NMR and Quasi Elastic Neutron Scattering and applied in Lithium-Sulfur Batteriescitations
- 2018Lithium Conductivity and Ions Dynamics in LiBH4/SiO2 Solid Electrolytes Studied by Solid-State NMR and Quasi-Elastic Neutron Scattering and Applied in Lithium Sulfur Batteries
- 2015Nanoconfined LiBH 4 as a Fast Lithium Ion Conductorcitations
- 2014Ionic conductivity and the formation of cubic CaH 2 in the LiBH 4 -Ca(BH 4 ) 2 compositecitations
- 2010Ammonia dynamics in magnesium ammine from DFT and neutron scatteringcitations
Places of action
Organizations | Location | People |
---|
article
Deciphering the Origin of Interface‐Induced High Li and Na Ion Conductivity in Nanocomposite Solid Electrolytes Using X‐Ray Raman Spectroscopy
Abstract
<jats:title>Abstract</jats:title><jats:p>Solid‐state electrolytes (SSEs) with high ionic conductivities are crucial for safer and high‐capacity batteries. Interface effects in nanocomposites of SSEs and insulators can lead to profound increases in conductivity. Understanding the composition of the interface is crucial for tuning the conductivity of composite solid electrolytes. Herein, X‐ray Raman Scattering (XRS) spectroscopy is used for the first time to unravel the nature of the interface effects responsible for conductivity enhancements in nanocomposites of complex hydride‐based electrolytes (LiBH<jats:sub>4</jats:sub>, NaBH<jats:sub>4</jats:sub>, and NaNH<jats:sub>2</jats:sub>) and oxides. XRS probe of the Li, Na, and B local environments reveals that the interface consists of highly distorted/defected and structurally distinct phase(s) compared to the original compounds. Interestingly, nanocomposites with higher concentrations of the interface compounds exhibit higher conductivities. Clear differences are observed in the interface composition of SiO<jats:sub>2</jats:sub>‐ and Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>‐based nanocomposites, attributed to differences in the reactivity of their surface groups. These results demonstrate that interfacial reactions play a dominant role in conductivity enhancement in composite solid electrolytes. This work showcases the potential of XRS in investigating interface interactions, providing valuable insights into the often complex ion conductor/insulator interfaces, especially for systems containing light elements such as Li, B, and Na present in most SSEs and batteries.</jats:p>