| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Wharton, Julian A.
University of Southampton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (27/27 displayed)
- 2024Solid polymer electrolytes with enhanced electrochemical stability for high-capacity aluminum batteriescitations
- 2023Heat treatment effects on the corrosion performance of wire arc additively manufactured ER316LSi stainless steelcitations
- 2023Surface properties influence marine biofilm rheology, with implications for ship dragcitations
- 2018Explicit fracture modelling of cemented tungsten carbide (WC-Co) at the mesoscalecitations
- 2016Electrochemical detection of cupric ions with boron-doped diamond electrode for marine corrosion monitoringcitations
- 2015Electrochemical detection of cupric ions with boron-doped diamond electrode for corrosion monitoring
- 2013Pseudotumour formation due to tribocorrosion at the taper interface of large diameter metal on polymer modular total hip replacementscitations
- 2013A review of the manufacture, mechanical properties and potential applications of auxetic foamscitations
- 2013Characterisation of crevice and pit solution chemistries using capillary electrophoresis with contactless conductivity detectorcitations
- 2012Effect of abrasive particle size and the influence of microstructure on the wear mechanisms in wear-resistant materialscitations
- 2012A novel microfluidic approach for the assessment of antifouling technologies
- 2010Interpretation of electrochemical measurements made during micro-scale abrasion-corrosioncitations
- 2010Designing biomimetic antifouling surfacescitations
- 2010Electrodeposition and tribological characterisation of nickel nanocomposite coatings reinforced with nanotubular titanatescitations
- 2009Surface potential effects on friction and abrasion of sliding contacts lubricated by aqueous solutionscitations
- 2009Microabrasion-corrosion of cast CoCrMo alloy in simulated body fluidscitations
- 2008Tribocorrosion damage of a Jethete M152 type stainless steelcitations
- 2008The effects of proteins and pH on tribo-corrosion performance of cast CoCrMo: a combined electrochemical and tribological studycitations
- 2007Exposure effects of alkaline drilling fluid on the microscale abrasion–corrosion of WC-based hardmetalscitations
- 2007Synergistic effects of micro-abrasion–corrosion of UNS S30403, S31603 and S32760 stainless steelscitations
- 2005Corrosion, erosion and erosion–corrosion performance of plasma electrolytic oxidation (PEO) deposited Al2O3 coatingscitations
- 2005The corrosion of nickel–aluminium bronze in seawater [in A Century of Tafel’s Equation: A Commemorative Issue of Corrosion Science]citations
- 2005Flow corrosion behaviour of austenitic stainless steels UNS S30403 and UNS S31603
- 2005Micro-abrasion-corrosion of a CoCrMo alloy in simulated artificial hip joint environmentscitations
- 2003Erosion and erosion-corrosion performance of cast and thermally sprayed nickel-aluminium bronze
- 2002Investigation of erosion-corrosion processes using electrochemical noise measurementscitations
- 2000Crevice corrosion studies using electrochemical noise measurements and a scanning electrode techniquecitations
Places of action
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article
Solid polymer electrolytes with enhanced electrochemical stability for high-capacity aluminum batteries
Abstract
Chloroaluminate ionic liquids are commonly used electrolytes in rechargeable aluminum batteries due to their ability to reversibly electrodeposit aluminum at room temperature. Progress in aluminum batteries is currently hindered by the limited electrochemical stability, corrosivity, and moisture sensitivity of these ionic liquids. Here, a solid polymer electrolyte based on 1-ethyl-3-methylimidazolium chloride-aluminum chloride, polyethylene oxide, and fumed silica is developed, exhibiting increased electrochemical stability over the ionic liquid while maintaining a high ionic conductivity of ≈13 mS cm−1. In aluminum–graphite cells, the solid polymer electrolytes enable charging to 2.8 V, achieving a maximum specific capacity of 194 mA h g−1 at 66 mA g−1. Long-term cycling at 2.7 V showed a reversible capacity of 123 mA h g−1 at 360 mA g−1 and 98.4% coulombic efficiency after 1000 cycles. Solid-state nuclear magnetic resonance spectroscopy measurements reveal the formation of five-coordinate aluminum species that crosslink the polymer network to enable a high ionic liquid loading in the solid electrolyte. This study provides new insights into the molecular-level design and understanding of polymer electrolytes for high-capacity aluminum batteries with extended potential limits.