693.932 PEOPLE
| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Ponce De León, C.
University of Southampton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (46/46 displayed)
- 2024Solid polymer electrolytes with enhanced electrochemical stability for high-capacity aluminum batteriescitations
- 2023Investigation of the properties influencing the deactivation of iron electrodes in iron-air batteriescitations
- 2023A mediated vanadium flow batterycitations
- 2022Nanocellulose-based flexible electrodes for safe and sustainable energy storage
- 2020Simulations of fluid flow, mass transport and current distribution in a parallel plate flow cell during nickel electrodepositioncitations
- 2020Aluminium-poly(3,4-ethylenedioxythiophene) rechargeable battery with ionic liquid electrolytecitations
- 2020Electrodeposition of platinum on 3D-printed titanium mesh to produce tailored, high area anodescitations
- 2020Photocatalytic degradation of methylene blue dye on reticulated vitreous carbon decorated with electrophoretically deposited TiO2 nanotubescitations
- 2019Improving the stability and discharge capacity of nanostructured Fe2O3/C anodes for iron-air batteries and investigation of 1-octhanethiol as an electrolyte additivecitations
- 2019Electrochemical degradation of Reactive Blue 19 dye by combining boron doped diamond and reticulated vitreous carbon electrodescitations
- 2019Removal of methylene blue from aqueous solutions using an Fe2+ catalyst and in-situ H2O2 generated at gas diffusion cathodescitations
- 2018The influence of iodate ion additions to the bath on the deposition of electroless nickel on mild steelcitations
- 2018A new procedure for the template synthesis of metal nanowirescitations
- 2018X-ray computed micro-tomography of reticulated vitreous carboncitations
- 2018Electro-polymerisation of 3,4-ethylenedioxythiophene on reticulated vitreous carbon in imidazolium-based chloroaluminate ionic liquid as energy storage materialcitations
- 2018A comparison of Pd/C, perovskite, and Ni-Fe hexacyanoferrate bifunctional oxygen catalysts, at different loadings and catalyst layer thicknesses on an oxygen gas diffusion electrodecitations
- 2018Mass-transfer measurements at porous 3D Pt-Ir/Ti electrodes in a direct borohydride fuel cellcitations
- 2018Developments in electrode designcitations
- 2018Decolourisation of reactive black-5 at an RVC substrate decorated with PbO2/ TiO2 nanosheets prepared by anodic electrodepositioncitations
- 2018Rechargeable multi-valent metal-air batteriescitations
- 2017A rechargeable, aqueous iron air battery with nanostructured electrodes capable of high energy density operationcitations
- 2017Enhancement of antibacterial efficiency at silver electrodeposited on coconut shell activated carbon by modulating pulse frequencycitations
- 20173D-printed porous electrodes for advanced electrochemical flow reactorscitations
- 2016Electrochemical degradation of RB-5 dye by anodic oxidation, electro-Fenton and by combining anodic oxidation–electro-Fenton in a filter-press flow cellcitations
- 2016Effect of RVC porosity on the performance of PbO2 composite coatings with titanate nanotubes for the electrochemical oxidation of azo dyescitations
- 2016The importance of the film structure during self-powered Ibuprofen salicylate drug release from polypyrrole electrodeposited on AZ31 Mgcitations
- 2015Anodic deposition of compact, freely-standing or microporous polypyrrole films from aqueous methanesulphonic acidcitations
- 2015The formation of nanostructured surfaces by electrochemical techniques: a range of emerging surface finishes. Part 2: examples of nanostructured surfaces by plating and anodising with their applicationscitations
- 2015Electrodeposited conductive polymers for controlled drug release: polypyrrolecitations
- 2015The development of Zn–Ce hybrid redox flow batteries for energy storage and their continuing challengescitations
- 2014Versatile electrochemical coatings and surface layers from aqueous methanesulfonic acidcitations
- 2014Electrodeposition of copper from mixed sulphate–chloride acidic electrolytes at rotating disc electrodecitations
- 2014Full factorial design applied to the synthesis of Pd-?Ag nanobars by the polyol method and the perspective for ethanol oxidationcitations
- 2014A review of the electrodeposition of metal matrix composite coatings by inclusion of particles in a metal layercitations
- 2013Developments in electrode materials and electrolytes for aluminium-air batteriescitations
- 2013Highlights during the development of electrochemical engineeringcitations
- 2012The corrosion behaviour of nanograined metals and alloyscitations
- 2012Degradation of paracetamol by advance oxidation processes using modified reticulated vitreous carbon electrodes with TiO2 and CuO/TiO2/Al2O3citations
- 2011The preparation of PbO2 coatings on reticulated vitreous carbon for the electro-oxidation of organic pollutantscitations
- 2011Electrodeposition of polypyrrole–titanate nanotube composites coatings and their corrosion resistancecitations
- 2010Copper deposition at segmented, reticulated vitreous carbon cathode in hull cellcitations
- 2006Modelling of the concentration–time relationship based on global diffusion-charge transfer parameters in a flow-by reactor with a 3D electrodecitations
- 2005The rotating cylinder electrode (RCE) and its application to the electrodeposition of metalscitations
- 2004The application of reticulated vitreous carbon rotating cylinder electrodes to the removal of cadmium and copper ions from solutioncitations
- 2002Electrochemical deposition of silver and gold from cyanide leaching solutionscitations
- 2002Electrochemical recovery of silver from cyanide leaching solutionscitations
Places of action
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article
Solid polymer electrolytes with enhanced electrochemical stability for high-capacity aluminum batteries
Abstract
Chloroaluminate ionic liquids are commonly used electrolytes in rechargeable aluminum batteries due to their ability to reversibly electrodeposit aluminum at room temperature. Progress in aluminum batteries is currently hindered by the limited electrochemical stability, corrosivity, and moisture sensitivity of these ionic liquids. Here, a solid polymer electrolyte based on 1-ethyl-3-methylimidazolium chloride-aluminum chloride, polyethylene oxide, and fumed silica is developed, exhibiting increased electrochemical stability over the ionic liquid while maintaining a high ionic conductivity of ≈13 mS cm−1. In aluminum–graphite cells, the solid polymer electrolytes enable charging to 2.8 V, achieving a maximum specific capacity of 194 mA h g−1 at 66 mA g−1. Long-term cycling at 2.7 V showed a reversible capacity of 123 mA h g−1 at 360 mA g−1 and 98.4% coulombic efficiency after 1000 cycles. Solid-state nuclear magnetic resonance spectroscopy measurements reveal the formation of five-coordinate aluminum species that crosslink the polymer network to enable a high ionic liquid loading in the solid electrolyte. This study provides new insights into the molecular-level design and understanding of polymer electrolytes for high-capacity aluminum batteries with extended potential limits.