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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Nielsch, Kornelius
Leibniz Institute for Solid State and Materials Research
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (56/56 displayed)
- 2024SnS2 Thin Film with In Situ and Controllable Sb Doping via Atomic Layer Deposition for Optoelectronic Applicationscitations
- 2024Low-Temperature ALD of SbOx/Sb2Te3 Multilayers with Boosted Thermoelectric Performancecitations
- 2024Structural, optical, and electrical characterization of TiO2-doped yttria-stabilized zirconia electrolytes grown by atomic layer deposition
- 2024Tailoring microstructure and properties of CuZrAl(Nb) metallic-glass–crystal composites and nanocrystalline alloys obtained by flash-annealingcitations
- 2023How to grow single-crystalline and epitaxial NiTi films in (100)- and (111)-orientation
- 2023Grain Boundary Phases in NbFeSb Half‐Heusler Alloys: A New Avenue to Tune Transport Properties of Thermoelectric Materialscitations
- 2023Solving the puzzle of hierarchical martensitic microstructures in NiTi by (111)-oriented epitaxial films
- 2023Influence of Lattice Mismatch on Structural and Functional Properties of Epitaxial Ba0.7Sr0.3TiO3 Thin Films
- 2023Enhancing the Thermoelectric Properties via Modulation of Defects in <i>P</i>‐Type MNiSn‐Based (M = Hf, Zr, Ti) Half‐Heusler Materialscitations
- 2023Exchange Bias Effect of Ni@(NiO,Ni(OH)2) Core/Shell Nanowires Synthesized by Electrochemical Deposition in Nanoporous Alumina Membranes
- 2023Exchange Bias Effect of Ni@(NiO,Ni(OH)2) Core/Shell Nanowires Synthesized by Electrochemical Deposition in Nanoporous Alumina Membranescitations
- 2022Low-Temperature Atomic Layer Deposition of High-k SbOx for Thin Film Transistorscitations
- 2022Mechanical behavior and deformation mechanism of shape memory bulk metallic glass composites synthesized by powder metallurgycitations
- 2022Anomalous Temperature-Dependent Behavior of Physical Properties of CrFeNi, CoCrNi, and CoCrFeNi Medium- and High-Entropy Alloyscitations
- 2022What is the speed limit of martensitic transformations?citations
- 2022Encapsulation of locally welded silver nanowire with water-free ALD-SbOx for flexible thin-film transistors
- 2022Aero-TiO2 Prepared on the Basis of Networks of ZnO Tetrapods
- 2022Electrocaloric temperature changes in epitaxial Ba1-xSrxTiO3 filmscitations
- 2022Comparative Study of Onion-like Carbons Prepared from Different Synthesis Routes towards Li-Ion Capacitor Applicationcitations
- 2022Phase-formation maps of CuZrAlCo metallic glass explored by in situ ultrafast techniquescitations
- 2022A role of atomic size misfit in lattice distortion and solid solution strengthening of TiNbHfTaZr high entropy alloy systemcitations
- 2022The Role of Al2O3 ALD Coating on Sn-Based Intermetallic Anodes for Rate Capability and Long-Term Cycling in Lithium-Ion Batteriescitations
- 2021Influence of Alumina Addition on the Optical Properties and the Thermal Stability of Titania Thin Films and Inverse Opals Produced by Atomic Layer Deposition
- 2021Phase constitution and microstructure of the NbTiVZr refractory high-entropy alloy solidified upon different processing
- 2021Interface-Dominated Topological Transport in Nanograined Bulk Bi2 Te3
- 2021Interface-Dominated Topological Transport in Nanograined Bulk Bi2 Te3citations
- 2021Current State-of-the-Art in the Interface/Surface Modification of Thermoelectric Materials
- 2021Structural and Electric Properties of Epitaxial Na0.5Bi0.5TiO3-Based Thin Filmscitations
- 2021Structural and Electric Properties of Epitaxial Na0.5Bi0.5TiO3-Based Thin Filmscitations
- 2021In situ study of non-equilibrium solidification of CoCrFeNi high-entropy alloy and CrFeNi and CoCrNi ternary suballoyscitations
- 2020Building Hierarchical Martensite
- 2020Control of positive and negative magnetoresistance in iron oxide−iron nanocomposite thin films for tunable magnetoelectric nanodevicescitations
- 2020Increasing the Diversity and Understanding of Semiconductor Nanoplatelets by Colloidal Atomic Layer Deposition
- 2020Heterostructured Bismuth Telluride Selenide Nanosheets for Enhanced Thermoelectric Performance
- 2020Wettability control of polymeric microstructures replicated from laser-patterned stampscitations
- 2020Ultra-high strength Co-Ta-B bulk metallic glasses: glass formation, thermal stability and crystallizationcitations
- 2020Stress and Microstructure Evolution in Mo Thin Films without or with Cover Layers during Thermal-Cycling
- 2020Control of Positive and Negative Magnetoresistance in Iron Oxide : Iron Nanocomposite Thin Films for Tunable Magnetoelectric Nanodevices
- 2020The Influence of Cu-Additions on the Microstructure, Mechanical and Magnetic Properties of MnAl-C Alloyscitations
- 2020Thermoelectric transport- and Hall measurements of low defect Sb2Te3 thin films grown by Atomic Layer Deposition ; Thermoelectric transport and Hall measurements of low defect Sb2Te3 thin films grown by atomic layer depositioncitations
- 2020Voltage-controlled on switching and manipulation of magnetization via the redox transformation of β-FeOOH nanoplatelets
- 2020Voltage‐Controlled Deblocking of Magnetization Reversal in Thin Films by Tunable Domain Wall Interactions and Pinning Sites
- 2020Entropy of Conduction Electrons from Transport Experimentscitations
- 2020Thermoelectric Characterization Platform for Electrochemically Deposited Materials
- 2019AuCuNiPdPt as a benchmark for high entropy alloys
- 2018BaZrxTi1-xO3 epitaxial thin films for electrocaloric investigationscitations
- 2018Universal scaling behavior of the upper critical field in strained FeSe0.7Te0.3 thin filmscitations
- 2018Probing the Martensitic Microstructure of Magnetocaloric Heusler Films by Synchrotron Diffractioncitations
- 2017Face Centred Cubic Multi-Component Equiatomic Solid Solutions in the Au-Cu-Ni-Pd-Pt Systemcitations
- 2017The influence of the in-plane lattice constant on the superconducting transition temperature of FeSe0.7Te0.3 thin films
- 2017Highly porous α-Al 2 O 3 ceramics obtained by sintering atomic layer deposited inverse opals
- 2016Structural and ferroelectric properties of epitaxial BaZrxTi1-xO3 thin filmscitations
- 2015Enhanced structural and phase stability of titania inverse opalscitations
- 2015Magnon contribution to the magnetoresistance of iron nanowires deposited using pulsed electrodepositioncitations
- 2015Mechanism that governs the electro-optic response of second-order nonlinear polymers on silicon substratescitations
- 2014Thermopower engineering of Bi2Te3 without alloying: the interplay between nanostructuring and defect activationcitations
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article
Grain Boundary Phases in NbFeSb Half‐Heusler Alloys: A New Avenue to Tune Transport Properties of Thermoelectric Materials
Abstract
<jats:title>Abstract</jats:title><jats:p>Many thermoelectric materials benefit from complex microstructures. Grain boundaries (GBs) in nanocrystalline thermoelectrics cause desirable reduction in the thermal conductivity by scattering phonons, but often lead to unwanted loss in the electrical conductivity by scattering charge carriers. Therefore, modifying GBs to suppress their electrical resistivity plays a pivotal role in the enhancement of thermoelectric performance, <jats:italic>zT</jats:italic>. In this work, different characteristics of GB phases in Ti‐doped NbFeSb half‐Heusler compounds are revealed using a combination of scanning transmission electron microscopy and atom probe tomography. The GB phases adopt a hexagonal close‐packed lattice, which is structurally distinct from the half‐Heusler grains. Enrichment of Fe is found at GBs in Nb<jats:sub>0.95</jats:sub>Ti<jats:sub>0.05</jats:sub>FeSb, but accumulation of Ti dopants at GBs in Nb<jats:sub>0.80</jats:sub>Ti<jats:sub>0.20</jats:sub>FeSb, correlating to the bad and good electrical conductivity of the respective GBs. Such resistive to conductive GB phase transition opens up new design space to decouple the intertwined electronic and phononic transport in thermoelectric materials.</jats:p>