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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Li, Yang
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2024Spin injection in graphene using ferromagnetic indium-cobalt van der Waals contacts
- 2024Sensitivity of G0 and stress-strain relation of geomaterials to grain shape and surface roughness
- 2024Triple-junction perovskite–perovskite–silicon solar cells with power conversion efficiency of 24.4%
- 2023Study of surface damage in silicon by irradiation with focused rubidium ions using a cold-atom ion sourcecitations
- 2023Near-surface characterization using Distributed Acoustic Sensing in an urban area: Granada, Spain
- 2023Bright circularly polarized photoluminescence in chiral layered hybrid lead-halide perovskitescitations
- 2023Evaporated Self‐Assembled Monolayer Hole Transport Layers: Lossless Interfaces in <i>p‐i‐n</i> Perovskite Solar Cellscitations
- 2023Silver contamination and its toxicity and risk management in terrestrial and aquatic ecosystemscitations
- 2022Fiber orientation dependence of tribological behavior of short carbon fiber reinforced ceramic matrix compositescitations
- 2022Elastic and inelastic mean free paths for scattering of fast electrons in thin-film oxidescitations
- 2021Premelting and formation of ice due to Casimir-Lifshitz interactions: Impact of improved parameterization for materials ; ENEngelskEnglishPremelting and formation of ice due to Casimir-Lifshitz interactions: Impact of improved parameterization for materialscitations
- 2021Exciton versus free carrier emission: Implications for photoluminescence efficiency and amplified spontaneous emission thresholds in quasi-2D and 3D perovskitescitations
- 2020Rapid and cytocompatible cell-laden silk hydrogel formation via riboflavin-mediated crosslinking
- 2020Rapid and cytocompatible cell-laden silk hydrogel formation via riboflavin-mediated crosslinkingcitations
- 2019Electrochemical metallization ReRAMs (ECM) - Experiments and modellingcitations
- 2019Volumetric Bioprinting of Complex Living-Tissue Constructs within Secondscitations
- 2018Magnetically activated microcapsules as controlled release carriers for a liquid PDMS cross-linkercitations
- 2016Transient phases during fast crystallization of organic thin films from solutioncitations
- 2014Design of anodic aluminum oxide rear surface plasmonic heterostructures for light trapping in thin silicon solar cellscitations
- 2012Characterization of epitaxial GaAs MOS capacitors using atomic layer-deposited TiO2/Al2O3gate stack: study of Ge auto-doping and p-type Zn doping
- 2009Lanthanide N,N '-piperazine-bis(methylenephosphonates) (Ln = La, Ce, Nd) that display flexible frameworks, reversible hydration and cation exchangecitations
- 2007Confinement of Thermoresponsive Hydrogels in Nanostructured Porous Silicon Dioxide Templatescitations
- 2007Confinement of Thermoresponsive Hydrogels in Nanostructured Porous Silicon Dioxide Templatescitations
- 2005Synthesis and characterization of CdS quantum dots in polystyrene microbeadscitations
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article
Evaporated Self‐Assembled Monolayer Hole Transport Layers: Lossless Interfaces in <i>p‐i‐n</i> Perovskite Solar Cells
Abstract
<jats:title>Abstract</jats:title><jats:p>Engineering of the interface between perovskite absorber thin films and charge transport layers has fueled the development of perovskite solar cells (PSCs) over the past decade. For <jats:italic>p‐i‐n</jats:italic> PSCs, the development and adoption of hole transport layers utilizing self‐assembled monolayers (SAM‐HTLs) based on carbazole functional groups with phosphonic acid anchoring groups has enabled almost lossless contacts, minimizing interfacial recombination to advance power conversion efficiency in single‐junction and tandem solar cells. However, so far these materials have been deposited exclusively via solution‐based methods. Here, for the first time, vacuum‐based evaporation of the most common carbazole‐based SAM‐HTLs (2PACz, MeO‐2PACz, and Me‐4PACz) is reported. X‐ray photoelectron spectroscopy and infrared spectroscopy demonstrate no observable chemical differences in the evaporated SAMs compared to solution‐processed counterparts. Consequently, the near lossless interfacial properties are either preserved or even slightly improved as demonstrated via photoluminescence measurements and an enhancement in open‐circuit voltage. Strikingly, applying evaporated SAM‐HTLs to complete PSCs demonstrates comparable performance to their solution‐processed counterparts. Furthermore, vacuum deposition is found to improve perovskite wetting and fabrication yield on previously non‐ideal materials (namely Me‐4PACz) and to display conformal and high‐quality coating of micrometer‐sized textured surfaces, improving the versatility of these materials without sacrificing their beneficial properties.</jats:p>