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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Chen, Zhen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2023Nanostructured block copolymer single-ion conductors for low-temperature, high-voltage and fast charging lithium-metal batteriescitations
- 2022Polysiloxane‐Based Single‐Ion Conducting Polymer Blend Electrolyte Comprising Small‐Molecule Organic Carbonates for High‐Energy and High‐Power Lithium‐Metal Batteriescitations
- 2022Single-ion conducting polymer electrolyte for Li||LiNi0.6Mn0.2Co0.2O2 batteries—impact of the anodic cutoff voltage and ambient temperaturecitations
- 2021Single-ion conducting polymer electrolyte for Li||LiNi0.6Mn0.2Co0.2O2 batteries—impact of the anodic cutoff voltage and ambient temperaturecitations
- 2021Imaging the spin chirality of ferrimagnetic Néel skyrmions stabilized on topological antiferromagnetic Mn3Sncitations
- 2021Exploratory Study of Flexural Performance of Mechanically Recycled Glass Fiber Reinforced Polymer Shreds as Reinforcement in Cement Mortarcitations
- 2017Composition measurement in substitutionally disordered materials by atomic resolution energy dispersive X-ray spectroscopy in scanning transmission electron microscopycitations
- 2017The enhanced theta-prime (θ′) precipitation in an Al-Cu alloy with trace Au additionscitations
- 2015Energy dispersive X-ray analysis on an absolute scale in scanning transmission electron microscopycitations
- 2014Experimental study on the relationship of mechanic and hydraulic state variables, and the dielectric properties of clayscitations
Places of action
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article
Polysiloxane‐Based Single‐Ion Conducting Polymer Blend Electrolyte Comprising Small‐Molecule Organic Carbonates for High‐Energy and High‐Power Lithium‐Metal Batteries
Abstract
<jats:title>Abstract</jats:title><jats:p>Single‐ion conducting polymer electrolytes are considered particularly attractive for realizing high‐performance solid‐state lithium‐metal batteries. Herein, a polysiloxane‐based single‐ion conductor (PSiO) is investigated. The synthesis is performed via a simple thiol‐ene reaction, yielding flexible and self‐standing polymer electrolyte membranes (PSiOM) when blended with poly(vinylidene fluoride‐<jats:italic>co</jats:italic>‐hexafluoropropylene) (PVdF‐HFP). When incorporating 57 wt% of organic carbonates, these polymer membranes provide a Li<jats:sup>+</jats:sup> conductivity of >0.4 mS cm<jats:sup>−1</jats:sup> at 20 °C and a wide electrochemical stability window of more than 4.8 V. This excellent electrochemical stability allows for the highly reversible cycling of symmetric Li||Li cells as well as high‐energy Li||LiNi<jats:sub>0.6</jats:sub>Mn<jats:sub>0.2</jats:sub>Co<jats:sub>0.2</jats:sub>O<jats:sub>2</jats:sub> (NMC<jats:sub>622</jats:sub>) and Li||LiNi<jats:sub>0.8</jats:sub>Mn<jats:sub>0.1</jats:sub>Co<jats:sub>0.1</jats:sub>O<jats:sub>2</jats:sub> (NMC<jats:sub>811</jats:sub>) cells for several hundred cycles at relatively high discharge and charge rates. Remarkably, Li||NMC<jats:sub>811</jats:sub> cells with high mass loading cathodes provide more than 76% capacity retention at a high current density of 1.44 mA cm<jats:sup>−2</jats:sup>, thus rendering this polymer electrolyte suitable for high‐performance battery applications.</jats:p>