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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Armand, Michel
European Commission
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Transport Properties and Local Ions Dynamics in LATP‐Based Hybrid Solid Electrolytescitations
- 2022Interface Stability between Na3Zr2Si2PO12 Solid Electrolyte and Sodium Metal Anode for Quasi-Solid-State Sodium Batterycitations
- 2021Considering lithium-ion battery 3D-printing via thermoplastic material extrusion and polymer powder bed fusioncitations
- 2020Overview on Lithium-Ion Battery 3D-Printing By Means of Material Extrusioncitations
- 2020Poly(Ethylene Oxide)-LiTFSI Solid Polymer Electrolyte Filaments for Fused Deposition Modeling Three-Dimensional Printingcitations
- 2019Three-Dimensional Printing of a LiFePO4/Graphite Battery Cell via Fused Deposition Modelingcitations
- 2019Fluorine‐Free Noble Salt Anion for High‐Performance All‐Solid‐State Lithium–Sulfur Batteriescitations
- 2019Single-ion conducting poly(ethylene oxide carbonate) as solid polymer electrolyte for lithium batteriescitations
- 2018The effect of cation chemistry on physicochemical behaviour of superconcentrated NaFSI based ionic liquid electrolytes and the implications for Na battery performancecitations
- 2016Novel Na+ ion diffusion mechanism in mixed organic-inorganic ionic liquid electrolyte leading to high Na+ transference number and stable, high rate electrochemical cycling of sodium cellscitations
- 2016Stable zinc cycling in novel alkoxy-ammonium based ionic liquid electrolytescitations
- 2010Detailed studies on the fillers modification and their influence on composite, poly(oxyethylene)-based polymeric electrolytescitations
- 2009Ceramic-in-polymer versus polymer-in-ceramic polymeric electrolytes—A novel approachcitations
- 2009Modern generation of polymer electrolytes based on lithium conductive imidazole saltscitations
- 2007FLUOROSULPHONATED ELASTOMERS WITH LOW GLASS TRANSITION BASED OF VINYLIDENE FLUORIDE
Places of action
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article
Fluorine‐Free Noble Salt Anion for High‐Performance All‐Solid‐State Lithium–Sulfur Batteries
Abstract
<jats:title>Abstract</jats:title><jats:p>Amongst post‐Li‐ion battery technologies, lithium–sulfur (Li–S) batteries have captured an immense interest as one of the most appealing devices from both the industrial and academia sectors. The replacement of conventional liquid electrolytes with solid polymer electrolytes (SPEs) enables not only a safer use of Li metal (Li°) anodes but also a flexible design in the shape of Li–S batteries. However, the practical implementation of SPEs‐based all‐solid‐state Li–S batteries (ASSLSBs) is largely hindered by the shuttling effect of the polysulfide intermediates and the formation of dendritic Li° during the battery operation. Herein, a fluorine‐free noble salt anion, tricyanomethanide [C(CN)<jats:sub>3</jats:sub><jats:sup>−</jats:sup>, TCM<jats:sup>−</jats:sup>], is proposed as a Li‐ion conducting salt for ASSLSBs. Compared to the widely used perfluorinated anions {e.g., bis(trifluoromethanesulfonyl)imide anion, [N(SO<jats:sub>2</jats:sub>CF<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>)]<jats:sup>−</jats:sup>, TFSI<jats:sup>−</jats:sup>}, the LiTCM‐based electrolytes show decent ionic conductivity, good thermal stability, and sufficient anodic stability suiting the cell chemistry of ASSLSBs. In particular, the fluorine‐free solid electrolyte interphase layer originating from the decomposition of LiTCM exhibits a good mechanical integrity and Li‐ion conductivity, which allows the LiTCM‐based Li–S cells to be cycled with good rate capability and Coulombic efficiency. The LiTCM‐based electrolytes are believed to be the most promising candidates for building cost‐effective and high energy density ASSLSBs in the near future.</jats:p>