| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Zhang, Hong
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Helical interfacial modulation for perovskite photovoltaicscitations
- 2024Confined Flash Printing and Synthesis of Stable Perovskite Nanofilms under Ambient Conditions
- 2023Efficient, Near‐Infrared Light‐Induced Photoclick Reaction Enabled by Upconversion Nanoparticlescitations
- 2023Efficient, Near‐Infrared Light‐Induced Photoclick Reaction Enabled by Upconversion Nanoparticlescitations
- 2023Structure‐guided Capacitance Relationships in Oxidized Graphene Porous Materials Based Supercapacitors
- 2022Morphologic and Genomic Characteristics of Breast Cancers Occurring in Individuals with Lynch Syndromecitations
- 2022Tuning phase separation morphology in blend thin films using well-defined linear (multi)block copolymerscitations
- 2016A Series of Pyrene-Substituted Silicon Phthalocyanines as Near-IR Sensitizers in Organic Ternary Solar Cellscitations
- 2016A hyperbranched dopamine-containing PEG-based polymer for the inhibition of α-synuclein fibrillationcitations
- 2013Simulating lattice image of suspended graphene taken by Helium ion microscopy
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article
A Series of Pyrene-Substituted Silicon Phthalocyanines as Near-IR Sensitizers in Organic Ternary Solar Cells
Abstract
<jats:p>An attractive method to broaden the absorption bandwidth of polymer/fullerene‐based bulk heterojunction (BHJ) solar cells is to blend near infrared (near‐IR) sensitizers into the host system. Axial substitution of silicon phthalocyanines (Pcs) opens a possibility to modify the chemical, thermodynamic, electronic, and optical properties. Different axial substitutions are already designed to modify the thermodynamic properties of Pcs, but the impact of extending the <jats:italic>π</jats:italic>‐conjugation of the axial ligand on the opto‐electronic properties, as a function of the length of the alkyl spacer, has not been investigated yet. For this purpose, a novel series of pyrene‐substituted silicon phthalocyanines (SiPc‐Pys) with varying lengths of alkyl chain tethers are synthesized. The UV–vis and external quantum efficiency (EQE) results exhibit an efficient near IR sensitization up to 800 nm, clearly establishing the impact of the pyrene substitution. This yields an increase of over 20% in the short circuit current density (<jats:italic>J</jats:italic> <jats:sub>SC</jats:sub>) and over 50% in the power conversion efficiency (PCE) for the dye‐sensitized ternary device. Charge generation, transport properties, and microstructure are studied using different advanced technologies. Remarkably, these results provide guidance for the diverse and judicious selection of dye sensitizers to overcome the absorption limitation and achieve high efficiency ternary solar cells.</jats:p>