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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hagfeldt, Anders
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2023Understanding and decoupling the role of wavelength and defects in light-induced degradation of metal-halide perovskitescitations
- 2022An open-access database and analysis tool for perovskite solar cells based on the FAIR data principlescitations
- 2022Experimental and theoretical study of organic sensitizers for solid-state dye-sensitized solar cells (s-DSSCs)citations
- 2022Thermodynamic stability screening of IR-photonic processed multication halide perovskite thin filmscitations
- 2021An open-access database and analysis tool for perovskite solar cells based on the FAIR data principlescitations
- 2021Photoelectrochemical Water‐Splitting Using CuO‐Based Electrodes for Hydrogen Production: A Reviewcitations
- 2021Photoelectrochemical water‐splitting using CuO‐based electrodes for hydrogen production : a review
- 2021Outstanding passivation effect by a mixed-salt interlayer with internal interactions in perovskite solar cellscitations
- 2020Interfacial and bulk properties of hole transporting materials in perovskite solar cells: spiro-MeTAD versus spiro-OMeTADcitations
- 2019PbZrTiO3 ferroelectric oxide as an electron extraction material for stable halide perovskite solar cellscitations
- 2018Perovskite Solar Cells: From the Atomic Level to Film Quality and Device Performancecitations
- 2018Interfacial engineering of metal oxides for highly stable halide perovskite solar cellscitations
- 2017Migration of cations induces reversible performance losses over day/night cycling in perovskite solar cellscitations
- 2017Monolithic CIGS-perovskite tandem cell for optimal light harvesting without current matchingcitations
- 2016Carbon nanotube-based hybrid hole-transporting material and selective contact for high efficiency perovskite solar cellscitations
- 2016A New 1,3,4-Oxadiazole-Based Hole-Transport Material for Efficient CH3NH3PbBr3 Perovskite Solar Cellscitations
- 2016Not all that glitters is gold: metal-migration-induced degradation in perovskite solar cellscitations
- 2015Transparent Cuprous Oxide Photocathode Enabling a Stacked Tandem Cell for Unbiased Water Splittingcitations
- 2013Dye sensitised solar cells with nickel oxide photocathodes prepared via scalable microwave sinteringcitations
- 2006Sensitized Hole Injection of Phosphorus Porphyrin into NiO: Toward New Photovoltaic Devicescitations
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article
Transparent Cuprous Oxide Photocathode Enabling a Stacked Tandem Cell for Unbiased Water Splitting
Abstract
Photoelectrochemical water splitting represents an attractive method of capturing and storing the immense energy of sunlight in the form of hydrogen, a clean chemical fuel. Given the large energetic demand of water electrolysis, and the defined spectrum of photons available from incident sunlight, a two absorber tandem device is required to achieve high efficiencies. The two absorbers should be of different and complementary bandgaps, connected in series to achieve the necessary voltage, and arranged in an optical stack configuration to maximize the utilization of sunlight. This latter requirement demands a top device that is responsive to high-energy photons but also transparent to lower-energy photons, which pass through to illuminate the bottom absorber. Here, cuprous oxide (Cu2O) is employed as a top absorber component, and the factors influencing the balance between transparency and efficiency toward operation in a tandem configuration are studied. Photocathodes based on Cu2O electrodeposited onto conducting glass substrates treated with thin, discontinuous layers of gold achieve reasonable sub-bandgap transmittance while retaining performances comparable to their opaque counterparts. This new high-performance transparent photocathode is demonstrated in tandem with a hybrid perovskite photovoltaic cell, resulting in a full device capable of standalone sunlight-driven water splitting.