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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Jørgensen, Mikkel
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (34/34 displayed)
- 2024Biocomposite Films of Amylose Reinforced with Polylactic Acid by Solvent Casting Method Using a Pickering Emulsion Approachcitations
- 2016The Organic Power Transistor: Roll-to-Roll Manufacture, Thermal Behavior, and Power Handling When Driving Printed Electronicscitations
- 2015Matrix Organization and Merit Factor Evaluation as a Method to Address the Challenge of Finding a Polymer Material for Roll Coated Polymer Solar Cellscitations
- 2015Matrix Organization and Merit Factor Evaluation as a Method to Address the Challenge of Finding a Polymer Material for Roll Coated Polymer Solar Cellscitations
- 2015Roll-to-Roll Printed Silver Nanowire Semitransparent Electrodes for Fully Ambient Solution-Processed Tandem Polymer Solar Cellscitations
- 2015Making Ends Meet: Flow Synthesis as the Answer to Reproducible High-Performance Conjugated Polymers on the Scale that Roll-to-Roll Processing Demandscitations
- 2014TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices – the ISOS-3 inter-laboratory collaborationcitations
- 2013Roll-to-Roll Inkjet Printing and Photonic Sintering of Electrodes for ITO Free Polymer Solar Cell Modules and Facile Product Integrationcitations
- 2013Roll-to-Roll Inkjet Printing and Photonic Sintering of Electrodes for ITO Free Polymer Solar Cell Modules and Facile Product Integrationcitations
- 2013All polymer photovoltaics: From small inverted devices to large roll-to-roll coated and printed solar cellscitations
- 2013All polymer photovoltaics: From small inverted devices to large roll-to-roll coated and printed solar cellscitations
- 2013Non-destructive lateral mapping of the thickness of the photoactive layer in polymer-based solar cellscitations
- 2013A laboratory scale approach to polymer solar cells using one coating/printing machine, flexible substrates, no ITO, no vacuum and no spincoatingcitations
- 2012TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices - the ISOS-3 inter-laboratory collaborationcitations
- 2012Stability of Polymer Solar Cellscitations
- 2012Silver front electrode grids for ITO-free all printed polymer solar cells with embedded and raised topographies, prepared by thermal imprint, flexographic and inkjet roll-to-roll processescitations
- 2012Silver front electrode grids for ITO-free all printed polymer solar cells with embedded and raised topographies, prepared by thermal imprint, flexographic and inkjet roll-to-roll processescitations
- 2012High-throughput roll-to-roll X-ray characterization of polymer solar cell active layerscitations
- 2012Aesthetically Pleasing Conjugated Polymer: Fullerene Blends for Blue-Green Solar Cells Via Roll-to-Roll Processingcitations
- 2012TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices – the ISOS-3 inter-laboratory collaborationcitations
- 2012TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices – the ISOS-3 inter-laboratory collaborationcitations
- 2012TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devicescitations
- 2012Simultaneous multilayer formation of the polymer solar cell stack using roll-to-roll double slot-die coating from watercitations
- 2012Simultaneous multilayer formation of the polymer solar cell stack using roll-to-roll double slot-die coating from watercitations
- 2011Aqueous Processing of Low-Band-Gap Polymer Solar Cells Using Roll-to-Roll Methodscitations
- 2011Aqueous Processing of Low-Band-Gap Polymer Solar Cells Using Roll-to-Roll Methodscitations
- 2011Fused thiophene/quinoxaline low band gap polymers for photovoltaic's with increased photochemical stabilitycitations
- 2011Roll-to-Roll Processing of Inverted Polymer Solar Cells using Hydrated Vanadium(V)Oxide as a PEDOT:PSS Replacementcitations
- 2011ITO-free flexible polymer solar cells: From small model devices to roll-to-roll processed large modulescitations
- 2010Upscaling of polymer solar cell fabrication using full roll-to-roll processingcitations
- 2010Product integration of compact roll-to-roll processed polymer solar cell modules: methods and manufacture using flexographic printing, slot-die coating and rotary screen printingcitations
- 2009Structural determination of ethylene-propylene-diene rubber (EPDM) containing high degree of controlled long-chain branchingcitations
- 2009Thermo-cleavable solvents for printing conjugated polymers: Application in polymer solar cellscitations
- 2006Lifetimes of organic photovoltaics: Design and synthesis of single oligomer molecules in order to study chemical degradation mechanismscitations
Places of action
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article
Making Ends Meet: Flow Synthesis as the Answer to Reproducible High-Performance Conjugated Polymers on the Scale that Roll-to-Roll Processing Demands
Abstract
Continuous flow methods are employed for the controlled polymerization of the roll-to-roll (R2R) compatible polymer PBDTTTz-4 including optimization and upscaling experiments. The polymerization rate and materials’ quality can be increased significantly with the continuous fl ow method where reaction times down to 10 min afforded PBDTTTz-4 with high molecular weight and a constant quality. The flow method enables full control of the molecular weight via tuning of the flow speed, catalyst loading, and temperature and avoids variation in materials’ quality associated with conventional batch synthesis. Upscaling from 300 mg batch synthesis to 10 g flow synthesis affords PBDTTTz-4 with a production rate of up to 120 g day −1 for a very simple in-house build flow reactor. An average power conversion efficiency (PCE) of 3.5% is achieved on a small scale (1 cm 2 ) and an average PCE of 3.3% is achieved on a large scale (29 cm2 ). This shows that small device efficiencies can be scaled when using full R2R processing of flexible and encapsulated carbon-based modules without the use of vacuum, indium-tin-oxide, or silver, with the best achieving a PCE of 3.8% PCE.