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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Duclairoir, Florence
CEA Grenoble
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2023Toward the Improvement of Silicon-Based Composite Electrodes via an In-Situ Si@C-Graphene Composite Synthesis for Li-Ion Battery Applicationscitations
- 2016Non-conductive ferromagnets based on core double-shell nanoparticles for radio-electric applicationscitations
- 2016Non-conductive ferromagnets based on core double-shell nanoparticles for radio-electric applications
- 2015New Approach to Closely Spaced Disordered Cobalt-Graphene Polymer Nanocomposites for Non-Conductive RF Ferromagnetic Filmscitations
- 2015Core double–shell cobalt/graphene/polystyrene magnetic nanocomposites synthesized by in situ sonochemical polymerizationcitations
- 2015Core double-shell cobalt/graphene/polystyrene magnetic nanocomposites synthesized by in situ sonochemical polymerizationcitations
- 2013Nanosilicon-based thick negative composite electrodes for lithium batteries with graphene as conductive additivecitations
- 2013Nanosilicon-Based Thick Negative Composite Electrodes for Lithium Batteries with Graphene as Conductive Additivecitations
- 2013Nanosilicon‐Based Thick Negative Composite Electrodes for Lithium Batteries with Graphene as Conductive Additivecitations
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article
Nanosilicon-based thick negative composite electrodes for lithium batteries with graphene as conductive additive
Abstract
<p>Reduced graphene oxide (rGO) is used as a conductive additive for nanosilicon-based lithium battery anodes with the high active-mass loading typically required for industrial applications. In contrast to conventional Si electrodes that use acetylene black (AcB) as an additive, the rGO system shows pronounced improvement of electrochemical performance, irrespective of the cycling conditions. With capacity limitation, the rGO system results in improved coulombic efficiency (99.9%) and longer cycle life than conventional electrodes. Upon cycling without capacity limitation, much higher discharge capacity is maintained (2000 mAh g<sup>-1</sup> after 100 cycles for 2.5 mg of Si cm<sup>-2</sup>). Used in conjunction with the bridging carboxymethyl cellulose binder, the crumpled and resilient rGO allows highly reversible functioning of the electrode in which the Si particles repeatedly inflate and deflate upon alloying and dealloying with lithium.</p>