| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Ludwigs, Sabine
University of Stuttgart
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2023Autonomous Adaption of Intelligent Humidity‐Programmed Hydrogel Patches for Tunable Stiffness and Drug Releasecitations
- 2020Hybrid spintronic materials from conducting polymers with molecular quantum bits
- 2019From Isotropic to Anisotropic Conductivities in P(NDI2OD-T2) by (Electro-)Chemical Doping Strategiescitations
- 2019Triphenylamine and some of its derivatives as versatile building blocks for organic electronic applicationscitations
- 2016Achieving 6.7% Efficiency in P3HT/Indene‐C70 Bisadduct Solar Cells through the Control of Vertical Volume Fraction Distribution and Optimized Regio‐Isomer Ratioscitations
- 2014High-Temperature Rubbing: A Versatile Method to Align π-Conjugated Polymers without Alignment Substratecitations
- 2011In situ electrochemical monitoring of selective etching in ordered mesoporous block-copolymer templatescitations
- 2010Soft-etch mesoporous hole-conducting block copolymer templatescitations
- 2010Control of gyroid forming block copolymer templatescitations
Places of action
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article
Achieving 6.7% Efficiency in P3HT/Indene‐C70 Bisadduct Solar Cells through the Control of Vertical Volume Fraction Distribution and Optimized Regio‐Isomer Ratios
Abstract
Indene C60 and C70 bisadducts (IC60BA and IC70BA) have relatively high lowest unoccupied molecular orbital energies. In poly(3‐hexylthiophene) (P3HT)‐based polymer solar cells (PSCs), this produces an increase in open‐circuit voltage (VOC) and power conversion efficiency (PCE). However, ICBA synthesis produces a mixture of regio‐isomers with different indene spatial orientations (2, 5, and 12 o'clock) that alter the IC70BA molecular packing when mixed with P3HT. In this paper, how the IC70BA regio‐isomerism affects the PSC performance is examined by investigating the molecular packing of P3HT:IC70BA layers with different regio‐isomeric ratios. For the first time, non‐destructive spectroscopic ellipsometry is used to investigate the effect of the fabrication conditions on the P3HT/IC70BA vertical volume fraction distribution and the results are attributed to the spatial arrangement of the regio‐isomers. It is demonstrated that this unambiguously affects the PSC performance. As a result, record device efficiencies are repeatedly attained for standard architecture P3HT:IC70BA PSCs with photoactive areas of 0.43 cm2, achieving 5.9 (±0.4)% PCE (n = 15). With control of the IC70BA constituent, device PCEs vary from below 2.2% to peak values above 6.7%, among the highest recorded PCEs for a P3HT combination, highlighting the importance of the molecular phase separation for high‐efficiency devices.