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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bjørnetun Haugen, Astri
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2024Temperature-Dependent Ferroelectric Properties and Aging Behavior of Freeze-Cast Bismuth Ferrite-Barium Titanate Ceramicscitations
- 2023Interfacial Engineering of PVDF-TrFE toward Higher Piezoelectric, Ferroelectric, and Dielectric Performance for Sensing and Energy Harvesting Applicationscitations
- 2023Humidity resistance and recovery of sintered sodium potassium niobate-based piezoelectricscitations
- 2022Freeform injection molding of functional ceramics by hybrid additive manufacturingcitations
- 2022Piezoelectric properties of mechanochemically processed 0.67BiFeO3-0.33BaTiO3 ceramicscitations
- 2021Textured, lead-free piezoelectric ceramics with high figure of merit for energy harvestingcitations
- 2021Low-temperature synthesis of bismuth titanate by modified citrate amorphous methodcitations
- 2019Hybrid atmosphere processing of lead-free piezoelectric sodium potassium niobate-based ceramicscitations
- 2018Exploring the Processing of Tubular Chromite- and Zirconia-Based Oxygen Transport Membranescitations
- 2018Exploring the Processing of Tubular Chromite- and Zirconia-Based Oxygen Transport Membranescitations
- 2018Deposition of highly oriented (K,Na)NbO 3 films on flexible metal substratescitations
- 2018Deposition of highly oriented (K,Na)NbO3 films on flexible metal substratescitations
- 2017Oxygen transport properties of tubular Ce 0.9 Gd 0.1 O 1.95 -La 0.6 Sr 0.4 FeO 3−d composite asymmetric oxygen permeation membranes supported on magnesium oxidecitations
- 2017Ceramic processing of tubular, multilayered oxygen transport membranes (Invited)
- 2017Oxygen transport properties of tubular Ce0.9Gd0.1O1.95-La0.6Sr0.4FeO3−d composite asymmetric oxygen permeation membranes supported on magnesium oxidecitations
- 2016Graphite and PMMA as pore formers for thermoplastic extrusion of porous 3Y-TZP oxygen transport membrane supportscitations
- 2016Processing and characterization of multilayers for energy device fabrication (invited)
- 2015Tailoring of porosity of yttria-stabilized zirconia tubes as supports for oxygen separation membranes
- 2015Tailoring of porosity of yttria-stabilized zirconia tubes as supports for oxygen separation membranes
Places of action
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article
Interfacial Engineering of PVDF-TrFE toward Higher Piezoelectric, Ferroelectric, and Dielectric Performance for Sensing and Energy Harvesting Applications
Abstract
The electrical properties of pristine fluoropolymers are inferior due to their low polar crystalline phase content and rigid dipoles that tend to retain their fixed moment and orientation. Several strategies, such as electrospinning, electrohydrodynamic pulling, and template-assisted growing, have been proven to enhance the electrical properties of fluoropolymers; however, these techniques are mostly very hard to scale-up and expensive. Here, a facile interfacial engineering approach based on amine-functionalized graphene oxide (AGO) is proposed to manipulate the intermolecular interactions in poly(vinylidenefluoride-trifluoroethylene) (PVDF-TrFE) to induce β-phase formation, enlarge the lamellae dimensions, and align the micro-dipoles. The coexistence of primary amine and hydroxyl groups on AGO nanosheets offers strong hydrogen bonding with fluorine atoms, which facilitates domain alignment, resulting in an exceptional remnant polarization of 11.3 µC cm<sup>−2</sup>. PVDF-TrFE films with 0.1 wt.% AGO demonstrate voltage coefficient, energy density, and energy-harvesting figure of merit values of 0.30 Vm N<sup>−1</sup>, 4.75 J cm<sup>−3</sup>, and 14 pm<sup>3</sup> J<sup>−1</sup>, respectively, making it outstanding compared with state-of-the-art ceramic-free ferroelectric films. It is believed that this work can open-up new insights toward structural and morphological tailoring of fluoropolymers to enhance their electrical and electromechanical performance and pave the way for their industrial deployment in next-generation wearables and human-machine interfaces.