| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Jankowski, Piotr
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Unveiling the plating-stripping mechanism in aluminum batteries with imidazolium-based electrolytes:A hierarchical model based on experiments and ab initio simulationscitations
- 2023Boron‐Based Functional Additives Enable Solid Electrolyte Interphase Engineering in Calcium Metal Batterycitations
- 2023Boron‐Based Functional Additives Enable Solid Electrolyte Interphase Engineering in Calcium Metal Batterycitations
- 2023Boron-Based Functional Additives Enable Solid Electrolyte Interphase Engineering in Calcium Metal Batterycitations
- 2023Electrolytes for Zn Batteries:Deep Eutectic Solvents in Polymer Gelscitations
- 2023Unveiling the plating-stripping mechanism in aluminum batteries with imidazolium-based electrolytescitations
- 2022Dual Role of Mo 6 S 8 in Polysulfide Conversion and Shuttle for Mg–S Batteriescitations
- 2022Dual Role of Mo<sub>6</sub>S<sub>8</sub> in Polysulfide Conversion and Shuttle for Mg–S Batteriescitations
- 2022Boron-Based Functional Additives Enable Solid Electrolyte Interphase Engineering in Calcium Metal Batterycitations
- 2021Prospects for Improved Magnesocene-Based Magnesium Battery Electrolytescitations
- 2020Multi‐Electron Reactions Enabled by Anion‐Based Redox Chemistry for High‐Energy Multivalent Rechargeable Batteriescitations
- 2020Multi-electron reactions enabled by anion-participated redox chemistry for high-energy multivalent rechargeable batteriescitations
- 2020Multi‐electron reactions enabled by anion‐based redox chemistry for high‐energy multivalent rechargeable batteries
- 2018Snapshots of the Hydrolysis of Lithium 4,5-Dicyanoimidazolate-Glyme Solvates. Impact of Water Molecules on Aggregation Processes in Lithium-Ion Battery Electrolytescitations
- 2016Understanding of Lithium 4,5-Dicyanoimidazolate-Poly(ethylene oxide) System: Influence of the Architecture of the Solid Phase on the Conductivitycitations
Places of action
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article
Dual Role of Mo<sub>6</sub>S<sub>8</sub> in Polysulfide Conversion and Shuttle for Mg–S Batteries
Abstract
<jats:title>Abstract</jats:title><jats:p>Magnesium–Sulfur batteries are one of most appealing options among the post‐lithium battery systems due to its potentially high energy density, safe and sustainable electrode materials. The major practical challenges are originated from the soluble magnesium polysulfide intermediates and their shuttling between the electrodes, which cause high overpotentials, low sulfur utilization, and poor Coulombic efficiency. Herein, a functional Mo<jats:sub>6</jats:sub>S<jats:sub>8</jats:sub> modified separator is designed to effectively address these issues. Both the experimental results and density functional theory calculations show that the electrochemically active Mo<jats:sub>6</jats:sub>S<jats:sub>8</jats:sub> layer has a superior adsorption capability of polysulfides and simultaneously acts as a mediator to accelerate the polysulfide conversion kinetics. Remarkably, the magnesium–sulfur cell assembled with the functional separator delivers a high specific energy density (942.9 mA h g<jats:sup>−1</jats:sup> in the 1st cycle) and can be cycled at 0.2 C for 200 cycles with a Coulombic efficiency of 96%. This work demonstrates a new design concept toward high‐performance metal–sulfur batteries.</jats:p>