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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Januchta, Kacper
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2020Indentation cracking and deformation mechanism of sodium aluminoborosilicate glassescitations
- 2020Competitive effects of free volume, rigidity, and self-adaptivity on indentation response of silicoaluminoborate glassescitations
- 2019Revisiting the Dependence of Poisson’s Ratio on Liquid Fragility and Atomic Packing Density in Oxide Glassescitations
- 2019Structural dependence of chemical durability in modified aluminoborate glassescitations
- 2019Structural dependence of chemical durability in modified aluminoborate glassescitations
- 2019Breaking the Limit of Micro-Ductility in Oxide Glassescitations
- 2019Elasticity, hardness, and fracture toughness of sodium aluminoborosilicate glassescitations
- 2019Mechanical property optimization of a zinc borate glass by lanthanum dopingcitations
- 2018Deformation and cracking behavior of La2O3-doped oxide glasses with high Poisson's ratiocitations
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article
Breaking the Limit of Micro-Ductility in Oxide Glasses
Abstract
Oxide glasses are one of the most important engineering and functional material families owing to their unique features, such as tailorable physical properties. However, at the same time intrinsic brittleness has been their main drawback, which severely restricts many applications. Despite much progress, a breakthrough in developing ultra‐damage‐resistant and ductile oxide glasses still needs to be made. Here, a critical advancement toward such oxide glasses is presented. In detail, a bulk oxide glass with a record‐high crack resistance is obtained by subjecting a caesium aluminoborate glass to surface aging under humid conditions, enabling it to sustain sharp contact deformations under loads of ≈500 N without forming any strength‐limiting cracks. This ultra‐high crack resistance exceeds that of the annealed oxide glasses by more than one order of magnitude, making this glass micro‐ductile. In addition, a remarkable indentation behavior, i.e., a time‐dependent shrinkage of the indent cavity, is demonstrated. Based on structural analyses, a molecular‐scale deformation model to account for both the ultra‐high crack resistance and the time‐dependent shrinkage in the studied glass is proposed.