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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Volonakis, George
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Perovskite‐Inspired Cs₂AgBi₂I₉: A Promising Photovoltaic Absorber for Diverse Indoor Environmentscitations
- 2024Polaronic Mass Enhancement and Polaronic Excitons in Metal Halide Perovskitescitations
- 2024Extending tight-binding models from bulk to layered halide perovskites
- 2023Chemical Behavior and Local Structure of the Ruddlesden−Popper and Dion−Jacobson Alloyed Pb/Sn Bromide 2D Perovskitescitations
- 2023Ultimate 2D Perovskite-FA DJ 2D Perovskites with Maximum Symmetry
- 2023Novel 3D Cubic Topology in Hybrid Lead Halides with a Symmetric Aromatic Triammonium Exhibiting Water Stability
- 2023Photovoltaic and excitonic properties of novel perovskite-like materials.
- 2023Fine Structure of Excitons in Vacancy-Ordered Halide Double Perovskitescitations
- 2022Surfaces/interfaces in atomic-scale semiconductor devices: structural and electronic properties of Pb-free perovskites and charge transport materials.
- 2022Recent results on metal halide perovskites and their interfaces*
- 2022Influence of surface termination on the structural and electronic properties at the Pb-free perovskite/charge transport material interfaces
- 2022Pb-free halide perovskites for solar cells, light-emitting diodes, and photocatalystscitations
- 2022Atomistic studies of surface and interface properties in lead-free halide perovskite semiconductor devices
- 2022Short Aromatic Diammonium Ions Modulate Distortions in 2D Lead Bromide Perovskites for Tunable White-Light Emissioncitations
- 2021Interplay between structural and electronic properties at Pb-free perovskite/electron transport material interfaces
- 2021Ruddlesden-Popper-Phase Hybrid Halide Perovskite/Small-Molecule Organic Blend Memory Transistorscitations
- 2021Quasiparticle Band Structure and Phonon-Induced Band Gap Renormalization of the Lead-Free Halide Double Perovskite Cs2InAgCl6citations
- 2021Towards lead-free perovskite device architectures: interface simulations of tin-based heterostructures
- 2020Intrinsic quantum confinement in formamidinium lead triiodide perovskitecitations
- 2018High‐Efficiency Fullerene Solar Cells Enabled by a Spontaneously Formed Mesostructured CuSCN‐Nanowire Heterointerfacecitations
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article
High‐Efficiency Fullerene Solar Cells Enabled by a Spontaneously Formed Mesostructured CuSCN‐Nanowire Heterointerface
Abstract
<jats:title>Abstract</jats:title><jats:p>Fullerenes and their derivatives are widely used as electron acceptors in bulk‐heterojunction organic solar cells as they combine high electron mobility with good solubility and miscibility with relevant semiconducting polymers. However, studies on the use of fullerenes as the sole photogeneration and charge‐carrier material are scarce. Here, a new type of solution‐processed small‐molecule solar cell based on the two most commonly used methanofullerenes, namely [6,6]‐phenyl‐C61‐butyric acid methyl ester (PC<jats:sub>60</jats:sub>BM) and [6,6]‐phenyl‐C71‐butyric acid methyl ester (PC<jats:sub>70</jats:sub>BM), as the light absorbing materials, is reported. First, it is shown that both fullerene derivatives exhibit excellent ambipolar charge transport with balanced hole and electron mobilities. When the two derivatives are spin‐coated over the wide bandgap p‐type semiconductor copper (I) thiocyanate (CuSCN), cells with power conversion efficiency (PCE) of ≈1%, are obtained. Blending the CuSCN with PC<jats:sub>70</jats:sub>BM is shown to increase the performance further yielding cells with an open‐circuit voltage of ≈0.93 V and a PCE of 5.4%. Microstructural analysis reveals that the key to this success is the spontaneous formation of a unique mesostructured p–n‐like heterointerface between CuSCN and PC<jats:sub>70</jats:sub>BM. The findings pave the way to an exciting new class of single photoactive material based solar cells.</jats:p>