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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Katančić, Zvonimir
European Commission
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Pristine and UV-Weathered PET Microplastics as Water Contaminants: Appraising the Potential of the Fenton Process for Effective Remediationcitations
- 2024Inkjet printed acrylate-urethane modified poly(3,4-ethylenedioxythiophene) flexible conductive films
- 2022Intrinsically Stretchable Poly(3,4-ethylenedioxythiophene) Conducting Polymer Film for Flexible Electronicscitations
- 2021Solar Light Activation of Persulfate by TiO<sub>2</sub>/Fe<sub>2</sub>O<sub>3</sub> Layered Composite Films for Degradation of Amoxicillin: Degradation Mechanism, Matrix Effects, and Toxicity Assessmentscitations
- 2021Solar Light Activation of Persulfate by TiO2 / Fe2O3 Layered Composite Films for Degradation of Amoxicillin: Degradation Mechanism, Matrix Effects, and Toxicity Assessmentscitations
- 2021Development of PE/PCL Bilayer Films Modified with Casein and Aluminum Oxidecitations
- 2019Efficiency of TiO2 catalyst supported by modified waste fly ash during photodegradation of RR45 dyecitations
- 2018Fly ash supported photocatalytic nanocomposite poly(3,4‐ethylenedioxythiophene)/TiO<sub>2</sub> for azo dye removal under simulated solar irradiationcitations
- 2014Thermal decomposition of fire-retarded high-impact polystyrene and high-impact polystyrene/ethylene–vinyl acetate blend nanocomposites followed by thermal analysiscitations
- 2014Effect of modified nanofillers on fire retarded high-density polyethylene/wood compositescitations
- 2012Influence of calcium carbonate filler and mixing type process on structure and properties of styrene–acrylonitrile/ethylene–propylene–diene polymer blendscitations
- 2011Effect of preparation on morphology-properties relationships in SAN/EPDM/PCC compositescitations
Places of action
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article
Solar Light Activation of Persulfate by TiO<sub>2</sub>/Fe<sub>2</sub>O<sub>3</sub> Layered Composite Films for Degradation of Amoxicillin: Degradation Mechanism, Matrix Effects, and Toxicity Assessments
Abstract
<jats:title>Abstract</jats:title><jats:p>In this study, sandwich‐type composites made of commercial TiO<jats:sub>2</jats:sub>‐P25 and α‐Fe<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> are obtained by spin coating thin films with different layer configurations, namely: i) TiO<jats:sub>2</jats:sub> layer over α‐Fe<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> (TiO<jats:sub>2</jats:sub>@α‐Fe<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>), ii) α‐Fe<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> layer over TiO<jats:sub>2</jats:sub> (α‐Fe<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>@TiO<jats:sub>2</jats:sub>), and iii) physically mixed 50% (w/w) of TiO<jats:sub>2</jats:sub>/Fe<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>. Photocatalytic activity under simulated solar irradiation of the aforementioned composites and their pure components is investigated for the degradation of amoxicillin (AMX) in the presence and absence of persulfate (PS). In both cases, TiO<jats:sub>2</jats:sub>@α‐Fe<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> sandwich‐type achieve the highest degradation rates of AMX and a marked effect of PS addition on the AMX degradation rate is noted. The influence of pH and PS concentration on AMX degradation rate is established by means of experimental design and response surface modeling. The AMX degradation pathway is studied by means of reactive oxygen species scavenging and identification of intermediates by liquid chromatography with tandem mass spectrometry. Their evolution is directly correlated with an increased toxicity assessed by <jats:italic>Daphnia magna</jats:italic> and <jats:italic>Vibrio fischeri</jats:italic> assays. Furthermore, biodegradability changes are correlated with the mineralization profile of AMX solution. The influence of water matrix constituents (Cl<jats:sup>−</jats:sup>, CO<jats:sub>3</jats:sub><jats:sup>2−</jats:sup>, NO<jats:sub>3</jats:sub><jats:sup>−</jats:sup>, PO<jats:sub>4</jats:sub><jats:sup>3−</jats:sup> and Suwannee river natural organic matter) on AMX degradation is established as well.</jats:p>